Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter FRP, Problem 3P
Interpretation Introduction
Interpretation:
The products formed from each of the given acid–base reactions are to be written.
Concept introduction:
舧 Acids are the substance that accepts a proton and form conjugate base.
舧 Bases are the substance that donates a proton and form conjugate acid.
舧 In acid–base reaction, acid and base react to form salt and water.
舧 The
舧 When sodium ethoxide reacts with phenol in acidic medium to form sodium phenoxide and ethanol as a side product.
舧 When sodium hydroxide reacts with phenol, formation of sodium phenoxide and water as a side product takes place.
舧 When sodium phenoxide reacts with the hydrochloric acid, formation of phenol and sodium chloride takes place.
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(a) Give chemical tests to distinguish between the following pairs of compounds :(i) Ethanal and Propanal (ii) Phenol and Benzoic acid(b) How will you bring about the following conversions?(i) Benzoic acid to benzaldehyde (ii) Ethanal to but-2-enal (iii) Propanone to propeneGive complete reaction in each case.
(a) Account for the following :(i) Propanal is more reactive than propanone towards nucleophilic reagents.(ii) Electrophilic substitution in benzoic acid takes place at meta position.(iii) Carboxylic acids do not give characteristic reactions of carbonyl group.(b) Give simple chemical test to distinguish between the following pairs of compounds:(i) Acetophenone and benzaldehyde(ii) Benzoic acid and ethylbenzoate.
(a) Give chemical tests to distinguish between(i) Phenol and Benzoic acid (ii) Benzophenone and Acetophenone
Chapter FRP Solutions
Organic Chemistry
Ch. FRP - Prob. 1PCh. FRP - 2. Which member of these pairs is the more polar?...Ch. FRP - Prob. 3PCh. FRP - Describe how solubility could be used to...Ch. FRP - 5. Though they each contain only one type of...Ch. FRP - Predict the products from each of the following...Ch. FRP - Prob. 7PCh. FRP - Prob. 8PCh. FRP - Prob. 9PCh. FRP - Prob. 10P
Ch. FRP - Predict the products from each of the following...Ch. FRP - Prob. 12PCh. FRP - 13. Starting with propyne and using any other...Ch. FRP - Bromination of 2-methylbutane yields predominantly...Ch. FRP - Prob. 15PCh. FRP - Account for the following observations with...Ch. FRP - Prob. 17PCh. FRP - Prob. 18PCh. FRP - Heating 1, 1,1-triphenylmethanol with ethanol...Ch. FRP - (a) Which of the following halides would you...Ch. FRP - An alkane (A) with the formula C6H14 reacts with...Ch. FRP - Prob. 22PCh. FRP - Prob. 23PCh. FRP - Dehydrohalogenation of meso-1, 2-dibromo-1,...Ch. FRP - Prob. 25PCh. FRP - Prob. 26PCh. FRP - 27. (R)-3-Methyl-1-pentene is treated separately...Ch. FRP - Prob. 28PCh. FRP - Prob. 29PCh. FRP - Prob. 30PCh. FRP - Prob. 31PCh. FRP - Synthesize the following compound by a method that...Ch. FRP - Provide three methods that employ Grignard...Ch. FRP - 34. Compound Yexhibits one NMR signal at (a...Ch. FRP - Prob. 35PCh. FRP - 36. Compound X shows a strong IR absorption band...Ch. FRP - Prob. 37PCh. FRP - 38. In addition to more highly fluorinated...Ch. FRP - Fluorination of (R)-2-flurobutane yields a mixture...Ch. FRP - Prob. 40PCh. FRP - Prob. 41P
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