Concept explainers
(a)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority
(b)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at the ring of carbon atoms.
(c)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with the locant number indicates the number of substituents and their respective position at the main chain or at the ring of carbon atoms.
(d)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at the ring of carbon atoms.
The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to the chiral center on the basis of the
(e)
Interpretation:
The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.
Concept introduction:
The root name in the given IUPAC name suggests the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at the ring of carbon atoms.
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EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
- Give detailed Solution with explanation neededarrow_forwardIUPAC: provide either names or structures a) N-ethyl-2-ethynyl-5-(prop-1-en-2-yl)aniline b) (R)-N-ethyl-N-methyl-N-propylprop-2-en- 1-aminium bromide c) B-D-xylopyranose d) a-L-sorbofuranose e) methyl B-D-gulopyranoside ) 3D structure of a natural dipeptide: Asp- Phe at neutral pl g) Br h) NHCH, INH Br i) NHCH,CH, j) NHCH, N.arrow_forwardQ.65.arrow_forward
- What reagents are needed to carry out the conversion shown? HO x HOCH₂CH₂OH, H₂SO4; CH3CH₂AICI 3 (2 eq.); H3O+ O HOCH₂CH₂CH₂OH, H₂SO4; CH3MgBr (4 eq.); H3O+ O HOCH₂CH₂CH₂CH₂CH₂CH₂OH, H₂SO4; H3O+ O HOCH₂CH₂OH, H₂SO4; CH3CH₂MgBr (2 eq.); H3O+ O HOCH₂CH₂CO3H; H3O+arrow_forwardDraw the organic products formed when cyclopentene is treated withfollowing reagent. [1] CH3CO3H; [2] H2O, HO−arrow_forwardDraw the structure of (S,S)-ethambutol, a drug used to treat tuberculosis that is 10 times more potent than any of its other stereoisomers.arrow_forward
- Give the structure corresponding to each name: (a) sec-butyl ethyl ketone; (b) methyl vinyl ketone; (c) p-ethylacetophenone; (d) 3-benzoyl-2-benzylcyclopentanone; (e) 6,6-dimethylcyclohex-2-enone; (f) 3-ethylhex-5-enal.arrow_forwardWhat is the major Organic product in the following reaction? CH;C. + CH NH, OH NCH, CH;C NHCH CH;CNHCH3 CH2-C NHCH CH,C. H. (c) (a) (b)arrow_forwardlejimalide B, an anticancer agent with a 24-membered ring, is isolated from a tunicate found off le Island in Okinawa. (a) Label each double bond in iejimalide B as E or Z. (b) Label each tetrahedral stereogenic center as R or S. (c) How many stereoisomers are possible for iejimalide B? CH;0 CHO OCH, HO, iejimalide Barrow_forward
- Ibufenac, a para-disubstituted arene with the structureHO2CCH2C6H4CH2CH(CH3)2 , is a much more potent analgesic thanaspirin, but it was never sold commercially because it caused livertoxicity in some clinical trials. Devise a synthesis of ibufenac frombenzene and organic halides having fewer than five carbons.arrow_forwardGive the IUPAC name for each aldehyde a. (CH:)2CHCH;CH;CH;CHO b. (CH:);CC(CH:)2CH;CHO CH;CH3 сно c. CH;CHCHCH;CH:CHCH; CH: d. CH3- C-CHCH;CH, е. CH3 CH;CH3 CH3 e. CH3(CH2)4CO2CH; f. CO,CH:CH; g. CH;CH;CH:CH;COOCH:CH2CH;arrow_forward1) 1544565- NH₂ 2) CI of & 7) 8) reagents used: FeCl3/Cl₂ HNO3/H₂SO4 MeCI/AICI3 ACCI/Et₂N SO3/H₂SO4 Pd/C, H₂ NaOH H₂SO4/heat ACCI= CI [Choose ]arrow_forward