Concept explainers
(a)
Interpretation:
For the given compound, the IUPAC name is to be assigned.
Concept introduction:
In naming organic compounds, the
Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on parent chain or ring is indicated by the respective locant number just before the suffix. The substituent groups are written in alphabetical order when writing the IUPAC name.
(b)
Interpretation:
For the given compound, the IUPAC name is to be assigned.
Concept introduction:
In naming organic compounds, the functional groups other than the highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing a functional group. Remove the “e” from the normal ‘ane’, ‘ene’, or ‘yne’ ending and add the suffix that corresponds to the highest-priority functional group. If ‘ester’ is present as the highest priority group attached directly to the ring, both the ring and the functional group establish the root name. The ring is named first followed by ‘carboxylate’. The group attached to O atom is written as a prefix to the root name.
Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of functional group and substituents on parent chain or ring is indicated by the respective locant number just before the suffix. The substituent groups are written in alphabetical order when writing the IUPAC name.
(c)
Interpretation:
For the given compound, the IUPAC name is to be assigned.
Concept introduction:
In naming organic compounds, the functional groups other than the highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing a functional group. Remove the “e” from the normal ‘ane’, ‘ene’, or ‘yne’ ending and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of functional group and substituents on parent chain or ring is indicated by the respective locant number just before the suffix. The substituent groups are written in alphabetical order when writing the IUPAC name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to the chiral center on the basis of the
(d)
Interpretation:
For the given compound, the IUPAC name is to be assigned.
Concept introduction:
In naming organic compounds, the functional groups other than the highest priority functional groups are treated as substituents. The root name is established by identifying the longest carbon chain or a ring containing a functional group. Remove the “e” from the normal ‘ane’, ‘ene’, or ‘yne’ ending and add the suffix that corresponds to the highest-priority functional group. If ‘ester’ is present as the highest priority group attached directly to the ring, both the ring and the functional group established the root name. The ring is named first followed by ‘carboxylate’. The group attached to O atom is written as a prefix to the root name.
Number the carbon chain in a way that the functional group and the substituents attached gets the lowest number. The position of functional group and substituents on parent chain or ring is indicated by the respective locant number just before the suffix. The substituent groups are written in alphabetical order when writing the IUPAC name.
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Chapter F Solutions
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
- Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H_ Br (S) CH 3 H3C (S) H Br A H Br 省 H3C (S) (R) CH₂ Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forward4. Which one of the following is trans-1-tert-butyl-3-methylcyclohexane in its most stable conformation? (NOTE: Correct answer must be trans- and must have a 1,3-arrangement of groups.) C(CH3)3 CH₁₂ A H,C D H₂C C(CH) C(CH3)3 C B CH C(CH) C(CH3)3 Earrow_forwardPredict the Product. Predict the major organic product for the following reaction:arrow_forward
- Nonearrow_forward3. Which one of the following is the lowest energy, most stable conformation of 1-bromopropane? H H H H H H H H CH3 HH Br H CH3 b b b b b CH3 A Br Br H H B CH3 Br H C H H H D CH3 H Br H E Harrow_forwardIn evolution, migration refers to the movement of alleles between populations. In your drawings, compare and contrast migration in evolutionary terms vs. in ecological terms. True Falsearrow_forward
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 31 I 1 :0: O: C 1 1 H Na Select to Add Arrows CH3CH2CCNa 1arrow_forwardgiven asp ...arrow_forwardNonearrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningWorld of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
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