(a) Interpretation: The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written. Concept introduction: The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC. In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester. The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 1

Question

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 3

Question

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 4

Question

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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Answer 5

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 6

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 7

Chapter F, Problem F.28P

Interpretation Introduction

(a)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for the given trivial name is to be drawn, and the correct IUPAC name is to be written.

Concept introduction:

The trivial names are commonly used names which are not systematic ones. Many trivial names are accepted by IUPAC.

In naming ester, the alkyl group is cited first, followed by the carboxylate group separated by a space. Thus, the general form of an ester name is alkyl alkanoate. The alkyl group bonded to the oxygen atom in ester and alkanoate is the part of carbonyl group. The alkan is the root name, and the suffix oate is added to the root name for the functional group ester.

The root name is established by identifying the longest carbon chain or a ring containing the functional group. Remove the e from the normal ane, ene, or yne ending, and add the suffix that corresponds to the highest-priority functional group. Number the carbon chain in a way that the functional group and the substituents attached get the lowest number. The position of the functional group and substituents on the parent chain or ring is indicated by the respective locant number just before the suffix. Prefixes are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The author explains the structure and IUPAC name for the given trivial name.

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