EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
2nd Edition
ISBN: 9780393630817
Author: KARTY
Publisher: W.W.NORTON+CO. (CC)
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Chapter E, Problem E.7P
Interpretation Introduction

(a)

Interpretation:

IUPAC name for the given molecule is to be written.

Concept introduction:

In the IUPAC naming the highest priority functional group is OH and they receive the suffix ‘ol’ after the final ‘e’ from the corresponding alkane. The chain or ring is numbered so that the OH group receives the lowest number. The -NH2 group is named using the ‘amino’ prefix. The name of the substituent attached to the parent chain is written as a prefix to the left side of the root. The chain is numbered such that the carbon atom, to which the substituent is attached, gets the lowest possible number. This number is written on the left side of the substituent and separated by a hyphen.

Interpretation Introduction

(b)

Interpretation:

IUPAC name for the given molecule is to be written.

Concept introduction:

In the IUPAC naming the highest priority functional group is OH and they receive the suffix ‘ol’ after the final ‘e’ from the corresponding alkane. The chain or ring is numbered so that the OH group receives the lowest number. The -NH2 group is named using the ‘amino’ prefix. The name of the substituent attached to the parent chain is written as a prefix to the left side of the root. The chain is numbered such that the carbon atom, to which the substituent is attached, gets the lowest possible number. This number is written on the left side of the substituent and separated by a hyphen.

Interpretation Introduction

(c)

Interpretation:

IUPAC name for the given molecule is to be written.

Concept introduction:

In the IUPAC naming the highest priority functional group is OH and they receive the suffix ‘ol’ after the final ‘e’ from the corresponding alkane. The chain or ring is numbered so that the OH group receives the lowest number. The -NH2 group is named using the ‘amino’ prefix. The name of the substituent attached to the parent chain is written as a prefix to the left side of the root. The chain is numbered such that the carbon atom, to which the substituent is attached, gets the lowest possible number. This number is written on the left side of the substituent and separated by a hyphen.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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