(a) Interpretation: The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified. Concept introduction: Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group . Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 1

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©

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Answer 2

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 3

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 4

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 5

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 6

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 7

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the structural formula of hexyl alcohol, which is based on the trivial names of the alkane to which the hydroxyl group is attached.

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Chapter E Solutions