(a) Interpretation: For the given compound, the IUPAC name is to be determined. Concept introduction: Follow the basic rules for naming compounds with two or more highest priority functional groups . Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

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Answer 1

Question

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

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Answer 3

Question

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

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Answer 4

Question

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

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Answer 5

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

Answer 6

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Answer 7

Chapter E, Problem E.10P

Interpretation Introduction

(a)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming compounds with two or more highest priority functional groups.

Determine the highest priority functional group present that calls for the suffix. Establish the longest chain or the ring that contains this functional group as the root. Number the root chain or ring so that the carbon atom to which this functional group is attached gets the least possible number. If there is more than one instance of the highest priority functional group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the final ‘e’ of ane, ene or yne in the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming of compounds with two or more instances of the highest priority group.

Determine the longest chain or the ring that contains the functional group as the root. Number the root so that the highest priority functional group gets the least possible number. If there are two or more instances of this group, add one locator for each instance, along with a di, tri, etc. to the suffix. Do not remove the ‘e’ from the root name prior to adding the suffix. All other functional groups are treated as substituents and appear in the name as prefixes along with their locators.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be determined.

Concept introduction:

Follow the basic rules for naming a compound with two or more instances of the huighest priority groups.

Determine the longest chain or the ring containing the highest priority group. Number the chain or ring so that the highest priority group gets the lowest number possible. If there are two or more instances of the highest priority groups, add one locator for each instance along with a di, tri, etc, to the suffix. Do not remove the final ‘e’ of the root name before adding the suffix. Treat all other functional groups present as substituents and list them in the alphabetical order in the prefix, along with their locators.

Answer 12

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the basic IUPAC rules for naming compounds with two or more highest-priority functional groups.

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