EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 8220100576379
Author: KARTY
Publisher: PEARSON
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Chapter E, Problem E.35P
Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

In an aldehyde, one side to the alkyl groups or aryl groups and on the other side to an H atom, the carbonyl carbon C=O is bonded. In the nomenclature of aldehyde, suffix “one” is added to the IUPAC name.

In the IUPAC name, the root name indicates the longest carbon chain at the end of the compound’s name. The suffix ‘al’ refers to the carbonyl group, (C=O), functional group. Any other alkyl groups, attached to the carbonyl carbon atom in an aldehyde, are treated as substituents and added in the name as a prefix. Other, lower priority, functional groups are listed as prefixes, along with numbers indicating their positions on the longest carbon chain. Prefixes, di, tri, etc., are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

In an aldehyde, one side to the alkyl groups or aryl groups and on the other side to an H atom, the carbonyl carbon C=O is bonded. In the nomenclature of aldehyde, suffix “one” is added to the IUPAC name.

In the IUPAC name, the root name indicates the longest carbon chain at the end of the compound’s name. The suffix ‘al’ refers to the carbonyl group, (C=O) functional group. Any other alkyl groups, attached to the carbonyl carbon atom in an aldehyde, are treated as substituents and added in the name as a prefixOther, lower priority, functional groups are listed as prefixes, along with numbers indicating their positions on the longest carbon chain. Prefixes, di, tri, etc., are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

In an aldehyde, one side to the alkyl groups or aryl groups and on the other side to an H atom, the carbonyl carbon C=O is bonded. In the nomenclature of aldehyde, suffix “one” is added to the IUPAC name.

In the IUPAC name, the root name indicates the longest carbon chain at the end of the compound’s name. The suffix ‘al’ refers to the carbonyl group, (C=O) functional group. Any other alkyl groups, attached to the carbonyl carbon atom in an aldehyde, are treated as substituents and added in the name as a prefix. Other, lower priority, functional groups are listed as prefixes, along with numbers indicating their positions on the longest carbon chain. Prefixes, di, tri, etc., are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

In an aldehyde, one side to the alkyl groups or aryl groups and on the other side to an H atom, the carbonyl carbon C=O is bonded. In the nomenclature of aldehyde, suffix “one” is added to the IUPAC name.

In the IUPAC name, the root name indicates the longest carbon chain at the end of the compound’s name. The suffix ‘al’ refers to the carbonyl (C=O) functional group. Any other alkyl groups, attached to the carbonyl carbon atom in an aldehyde, are treated as substituents and added in the name as a prefix. Other, lower priority, functional groups are listed as prefixes, along with numbers indicating their positions on the longest carbon chain. Prefixes, di, tri, etc., are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

Interpretation Introduction

(e)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

In an aldehyde, one side to the alkyl groups or aryl groups and on the other side to an H atom, the carbonyl carbon C=O is bonded. In the nomenclature of aldehyde, suffix “one” is added to the IUPAC name.

In the IUPAC name, the root name indicates the longest carbon chain at the end of the compound’s name. The suffix ‘al’ refers to the carbonyl (C=O) functional group. Any other alkyl groups, attached to the carbonyl carbon atom in an aldehyde, are treated as substituents and added in the name as a prefix. Other, lower priority, functional groups are listed as prefixes, along with numbers indicating their positions on the longest carbon chain. Prefixes, di, tri, etc., are used to denote the number of identical substituents. The substituents are written in alphabetical order when writing the IUPAC name.

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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