EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 8220100576379
Author: KARTY
Publisher: PEARSON
Question
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Chapter E, Problem E.26P
Interpretation Introduction

(a)

Interpretation:

The structure of the molecule that corresponds to the IUPAC name 3, 3-dipropoxypentan-1-amine is to be drawn.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group.

Interpretation Introduction

(b)

Interpretation:

The structure of the molecule that corresponds to the IUPAC name 2,3,4trichlorocyclohexanol  is to be drawn.

Concept introduction:

IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with the location numberss. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group.

Interpretation Introduction

(c)

Interpretation:

The structure of the molecule that corresponds to the IUPAC name 3-cyclopropylpentan-1-ol is to be drawn.

Concept introduction:

IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with the location numbers. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group.

Interpretation Introduction

(d)

Interpretation:

The structure of the molecule that corresponds to the IUPAC name 3-(1-methylethyl)cycloheptanamine  is to be drawn.

Concept introduction:

IUPAC name of a compound consists of three parts, prefix, root. and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with the location numbers. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

The suffix ‘ol’ refers to the alcohol functional group. The suffix ‘amino’ refers to the amine functional group.

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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