(a) Interpretation: The complete IUPAC name of the given molecule is to be written. Concept introduction: An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 1

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 3

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 4

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 5

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 6

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 7

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the IUPAC name of the given compound is determined on the basis of alkyl groups attached to the nitrogen atom.

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