(a) Interpretation: The complete IUPAC name of the given molecule is to be written. Concept introduction: An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 1

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 3

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 4

Question

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

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Answer 5

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 6

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 7

Chapter E, Problem E.25P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

An amine contains one to three alkyl and/or aryl groups bonded to a nitrogen atom. The largest alkyl or aryl group attached to the nitrogen forms the root. The suffix amine replaces the e at the end of the alkane name. A locant number is added between the root name and the suffix, unless redundant. The remaining alkyl and/or aryl groups are treated as substituents and named as prefixes in alphabetical order, with the locant N (for nitrogen). Any substituents on the alkyl/aryl groups are added as a prefix to the name of the respective alkyl/aryl group, including their locations. If two or all three groups linked to the nitrogen are identical, a prefix di or tri is used.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the IUPAC name of the given compound is determined on the basis of alkyl groups attached to the nitrogen atom.

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