(a) Interpretation: For the given molecule, the complete IUPAC name is to be written. Concept introduction: To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH 2 functional group, the functional group OH gets priority over NH 2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

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Answer 1

Question

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

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Answer 2

Question

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

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Answer 3

Question

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

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Answer 4

Question

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

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Answer 5

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 6

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 7

Chapter E, Problem E.28P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. In the molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes like ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The molecule that contains both, an OH and a NH2 functional group, the functional group OH gets priority over NH2 functional group, and the -ol is added as a suffix to the IUPAC name. Next, the main chain or ring containing the highest-priority functional group is to be determined. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’... etc. are used to indicate the number of identical substituents attached. The substituents are written in the alphabetical order.

Answer 12

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Answer 13

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the IUPAC name for the given molecule, which is 4-amino-3, 5-dichloropentan-1-ol.

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