(a) Interpretation: The structure from the given IUPAC name with appropriate stereochemistry is to be drawn. Concept introduction: The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group . The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms. The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1 → 2 → 3 is clockwise, the absolute configuration is R , and if it is counterclockwise, the absolute configuration is S .

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Answer 1

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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achieve.macmillanlearning.com Canvas EA eac h Hulu YouTube G 3 methyl cyclobutanol - Google Search Ranking Phenol Acidity Course -236 - Organic Chemistry - Mac... ← Assessment Completed 10 of 22 Questions 1 + Netflix paramount plus chem hw Galdehyde reaction with grignard reagent... b My Questions | bartleby M Inbox - chenteislegit@gmail.com - Gmail Due: Fri, Jan 31 Resources Solution Penalized ? Hint Submit Answer Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag the appropriate image to the correct position in the reactions.) Route 1 Aldehyde 1 or +98 Aldehyde 2 Route 2 Q6 +100 Solved in 1 attempt Q7 +95 Solved in 2 attempts Q8 +98 Unlimited attempts possible + + Grignard 1 OH H3O+ Grignard 2 Answer Bank Q9 +90 MgBr Unlimited attempts possible CH3CH2CH2MgBr Q10 Unlimited attempts Q11 ? ? +100 in 1 attempt 2-methyl-3-hexanol CH3CH2MgBr H H о H Attempt 3

2) (4 pt) After the reaction was completed, the student collected the following data. Crude product data is the data collected after the reaction is finished, but before the product is purified. "Pure" product data is the data collected after attempted purification using recrystallization. Student B's data: Crude product data "Pure" product data after recrystallization Crude mass: 0.93 g grey solid Crude mp: 96-106 °C Crude % yield: Pure mass: 0.39 g white solid Pure mp: 111-113 °C Pure % yield: a) Calculate the crude and pure percent yields for the student's reaction. b) Summarize what is indicated by the crude and pure melting points.

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Answer 2

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 3

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 4

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 5

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 6

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 7

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 10

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Answer 11

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Answer 13

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The structure of the given IUPAC name with appropriate stereochemistry is drawn. The root name indicates the main chain or ring of carbon atoms in the compound.

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Chapter E Solutions