(a) Interpretation: The IUPAC name for the given compound is to be determined. Concept introduction: In case of molecules containing a C=C or C ≡ C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present. If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C ≡ C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers. The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C ≡ C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Question

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Answer 1

Question

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

Question

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 3

Question

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 4

Question

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 5

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 6

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 7

Chapter B, Problem B.5P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

In case of molecules containing a C=C or C≡C bond, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. It is possible that the longest carbon chain has more carbons than specified by the root. But the double or triple bond must be a part of the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, the numbering begins from that end of the chain, which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

The carbon atoms having a double or triple bond between them are always assigned C1 and C2, if the root is a ring. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 12

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Answer 13

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Answer 23

Ch. B - Prob. B.1P Ch. B - Prob. B.2P Ch. B - Prob. B.3P Ch. B - Prob. B.4P Ch. B - Prob. B.5P Ch. B - Prob. B.6P Ch. B - Prob. B.7P Ch. B - Prob. B.8P Ch. B - Prob. B.9P Ch. B - Prob. B.10P

Solution Summary: The author explains that the IUPAC name for the given compound is 5, 5-dichloro-3-methoxycyclohexene.

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