Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter B, Problem B.34P
Interpretation Introduction

(a)

Interpretation:

The structure for hexylbenzene is to be drawn.

Concept introduction:

Benzene derivatives have one or more substituents attached to the benzene ring. In such compounds, the root name is benzene. The ring is numbered so that the substituents attached to it get the lowest locator numbers. Prefixes and locator numbers are used for writing the number and type of substituents.

Interpretation Introduction

(b)

Interpretation:

The structure for bromobenzene is to be drawn.

Concept introduction:

Benzene derivatives have one or more substituents attached to the benzene ring. In such compounds, the root name is benzene. The ring is numbered so that the substituents attached to it get the lowest locator numbers. Prefixes and locator numbers are used for writing the number and type of substituents.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC
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