Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter B, Problem B.40P
Interpretation Introduction

(a)

Interpretation:

The structure for 2-fluorotoluene is to be drawn.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene and the methoxy group in anisole.

Interpretation Introduction

(b)

Interpretation:

The structure for 4-ethoxytoluene is to be drawn.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene and the methoxy group in anisole.

Interpretation Introduction

(c)

Interpretation:

The structure for 2-ethoxyanisole is to be drawn.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene= and the methoxy group in anisole.

Interpretation Introduction

(d)

Interpretation:

The structure for 1, 3-diphenylheptane is to be drawn.

Concept introduction:

Benzene derivatives are named by considering the root as benzene. If the substituents attached to a benzene ring are complicated, it is easy to treat the benzene ring as a substituent instead of a root. These substituents are incorporated into the IUPAC name.

Interpretation Introduction

(e)

Interpretation:

The structure for 4, 4-diphenyl-1-octene is to be drawn.

Concept introduction:

Benzene derivatives are named by considering the root as benzene. If the substituents attached to a benzene ring are complicated, it is easy to treat the benzene ring as a substituent instead of a root. These substituents are incorporated into the IUPAC name.

Interpretation Introduction

(f)

Interpretation:

The structure for benzylbenzene is to be drawn.

Concept introduction:

Benzene derivatives are named by considering the root as benzene. If the substituents attached to a benzene ring are complicated, it is easy to treat the benzene ring as a substituent instead of a root. These substituents are incorporated into the IUPAC name.

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How might you prepare each of the following using a nucleophilic substitution reaction at some step? (a) (b) (c) (d) CH3 CH3C CCHCH3 CH3 CH3 0 CCH3 ☐ CH3 CH3CH2CH2CH2CN CH3CH2CH2NH2
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