(a) Interpretation: The IUPAC name for the given compound is to be determined. Concept introduction: For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C ≡ C groups. Number the chain or ring so that each successive C=C or C ≡ C group is encountered the earliest. For each pair of C=C or C ≡ C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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Answer 1

Question

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Answer 2

Question

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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Answer 3

Question

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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Answer 4

Question

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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Answer 5

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 6

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 7

Chapter B, Problem B.7P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be determined.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or C≡C groups. Number the chain or ring so that each successive C=C or C≡C group is encountered the earliest. For each pair of C=C or C≡C atoms, identify the lower of the two locator numbers. Immediately before the ene or yne suffix, add the letter ‘a’ followed by the above set of locator numbers, and then add the prefix di, tri, etc. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

Answer 12

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Answer 13

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Answer 15

Ch. B - Prob. B.1P Ch. B - Prob. B.2P Ch. B - Prob. B.3P Ch. B - Prob. B.4P Ch. B - Prob. B.5P Ch. B - Prob. B.6P Ch. B - Prob. B.7P Ch. B - Prob. B.8P Ch. B - Prob. B.9P Ch. B - Prob. B.10P

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