(a) Interpretation: The IUPAC name of the ether is to be written. Concept introduction: Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

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Answer 1

Question

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

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34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

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Answer 3

Question

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

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Answer 4

Question

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

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Answer 5

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

Answer 6

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Answer 7

Chapter A, Problem A.11P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix ‘-yl’ from the name of the corresponding alkyl group by the suffix ‘-oxy’.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy. If another substituent is present, the carbon bonded to the oxygen is numbered 1, and the rest of the chain carbons are numbered so as to give the lowest number to the substituent.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given ether is to be written.

Concept introduction:

Ethers are named as alkoxy substituted alkanes. An alkoxy group consists of an alkyl group attached to an oxygen atom. Out of the two alkyl groups in the ether, the longer continuous alkyl chain is treated as the root, with the shorter chain as part of the alkoxy group. The specific name for the substituent group is derived by replacing the suffix -yl from the name of the corresponding alkyl group by the suffix -oxy.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

Solution Summary: The IUPAC name of the given ether is ethoxypropane

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