ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
3rd Edition
ISBN: 9781119497479
Author: Klein
Publisher: WILEY
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Chapter 9.7, Problem 3LTS
Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given reaction by using its molecular structure.

Concept introduction:

Configuration: It is refer to the spatial arrangement of the atoms of a chiral molecular entire groups and its stereo chemical description.

R-S Configuration: The carbon bears right hand and left hand nomenclature is used to enantiomers of chiral atoms. The asymmetric or sterocenters labeled as R (Rectus) or S (Sinister) configuration.

Chiral center: The molecules having four different groups attached to central carbon atoms it is called chiral center.

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It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]
206 Pb 82 Express your answers as integers. Enter your answers separated by a comma. ▸ View Available Hint(s) VAΣ ΜΕ ΑΣΦ Np, N₁ = 82,126 Submit Previous Answers ? protons, neutrons

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