Chapter 9.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(b)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(d)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(e)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(f)

Interpretation Introduction

Interpretation:

To predict the major products for the given different reaction and transformations should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Soda amide: The strong base of ${\text{NaNH}}_{\text{2}}{\text{/NH}}_{\text{3}}$ will deprotonate alkynes, alcohols and other organic functional groups with acidic protons such as esters and ketones. It is also a very strong nucleophile. It is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of $\text{H-X}$ becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Anti-Markovnikov addition: These rules describe the regioselectivity (particular place in functional group) where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.