
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
5th Edition
ISBN: 9781260170405
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 9, Problem 9.8P
Draw the organic product of each reaction.
a. c.
b. d.
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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not
themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting
four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation
you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be
both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the
four structures.
Compound C
Possible conformations (circle one):
Дет
Lab Data
The distance entered is out of the expected range.
Check your calculations and conversion factors.
Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3?
Did you report your data to the correct number of significant figures?
- X
Experimental Set-up
HCI-NH3
NH3-HCI
Longer Tube
Time elapsed (min)
5 (exact)
5 (exact)
Distance between cotton balls (cm)
24.30
24.40
Distance to cloud (cm)
9.70
14.16
Distance traveled by HCI (cm)
9.70
9.80
Distance traveled by NH3 (cm)
14.60
14.50
Diffusion rate of HCI (cm/hr)
116
118
Diffusion rate of NH3 (cm/hr)
175.2
175.2
How to measure distance and calculate rate
For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically:
1:1 (one mole of EDTA per mole of metal ion)
2:1 (two moles of EDTA per mole of metal ion)
1:2 (one mole of EDTA per two moles of metal ion)
None of the above
Chapter 9 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
Ch. 9 - Problem 9.1 Label each ether and alcohol in...Ch. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Name each of the following ethers.Ch. 9 - Name each epoxide.
a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Problem 9.8 Draw the organic product of each...Ch. 9 - Prob. 9.9PCh. 9 - Problem 9.10 Draw the products of each reaction.
...
Ch. 9 - Problem 9.11 Draw the products formed when each...Ch. 9 - Prob. 9.12PCh. 9 - Problem 9.13 Draw the structure of each...Ch. 9 - What other alkene is also formed along with Y in...Ch. 9 - Prob. 9.15PCh. 9 - Explain why two substitution products are formed...Ch. 9 - Draw the products of each reaction. a. b. c.Ch. 9 - Problem 9.18 Draw the products of each reaction,...Ch. 9 - Problem 9.19 What is the major product formed...Ch. 9 - Prob. 9.20PCh. 9 - Prob. 9.21PCh. 9 - Problem 9.22 Draw the organic products formed in...Ch. 9 - Problem 9.23 Draw two steps to convert into each...Ch. 9 - Prob. 9.24PCh. 9 - Problem 9.25 Draw the products of each reaction,...Ch. 9 - Draw the products formed when (S)-butan-2-ol is...Ch. 9 - Draw the product formed when (CH3)2CHOH is treated...Ch. 9 - What alkyl halides are formed when each ether is...Ch. 9 - Explain why the treatment of anisole with HBr...Ch. 9 - Name each thiol.
a. b.
Ch. 9 - Draw the product of each reaction. ac b.d.Ch. 9 - Give the IUPAC name for each sulfide.
a. b.
Ch. 9 - Draw the product of each reaction.
a. b.
Ch. 9 - Prob. 9.34PCh. 9 - The cis and trans isomers of 2, 3-dimethyloxirane...Ch. 9 - Problem 9.36 Draw the product of each...Ch. 9 - 9.37 Name each compound depicted in the...Ch. 9 - Answer each question using the ball-and-stick...Ch. 9 - Prob. 9.39PCh. 9 - 9.40 Give IUPAC name for each...Ch. 9 - Prob. 9.41PCh. 9 - Prob. 9.42PCh. 9 - Prob. 9.43PCh. 9 - 9.44 Why is the boiling point of higher than...Ch. 9 - 9.45 Draw the organic product(s) formed when is...Ch. 9 - 9.46 What alkenes are formed when each alcohol is...Ch. 9 - Prob. 9.47PCh. 9 - 9.48 Draw the products of each reaction and...Ch. 9 - 9.49 Draw the product of the following reaction,...Ch. 9 - Prob. 9.50PCh. 9 - Prob. 9.51PCh. 9 - 9.52 Draw a stepwise mechanism for the following...Ch. 9 - 9.53 Although alcohol V gives a single alkene W...Ch. 9 - Prob. 9.54PCh. 9 - Prob. 9.55PCh. 9 - Prob. 9.56PCh. 9 - 9.57 Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 9.58PCh. 9 - 9.59 Draw two different routes to each of the...Ch. 9 - Prob. 9.60PCh. 9 -
9.61 Draw the products formed when each ether is...Ch. 9 - 9.62 Draw a stepwise mechanism for each...Ch. 9 - Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 9.64PCh. 9 - Draw the products of each reaction. a.c. b.d.Ch. 9 - When each halohydrin is treated with, a product of...Ch. 9 - Prob. 9.67PCh. 9 - Prob. 9.68PCh. 9 - Prob. 9.69PCh. 9 - Prob. 9.70PCh. 9 - Prepare each compound from cyclopentanol. More...Ch. 9 - 9.72 Identify the reagents (a–h) needed to carry...Ch. 9 - Prob. 9.73PCh. 9 - 9.74 Treatment of with affords compound A and ....Ch. 9 - Prob. 9.75PCh. 9 - Prob. 9.76PCh. 9 - 9.77 Draw a stepwise, detailed mechanism for the...Ch. 9 - 9.78 Dehydration of with affords
as a minor...Ch. 9 - Prob. 9.79PCh. 9 - 9.80 Draw a stepwise mechanism for the following...Ch. 9 -
9.81 Aziridines are heterocycles that contain an...
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