Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Question
Chapter 9, Problem 9.65QP
Interpretation Introduction
Interpretation:
The mass of MgCl2 present in a 60.0 mL 0.100 M MgCl2 solution has to be determined.
Concept introduction:
Mole
The mole of the solute is calculated by multiplication of concentration of solution and volume of the solution and it is,
Mole = Concentration (M)× volume (L)
The mass of compound is given by the multiplication of mole of the compound and molar mass of the compound in gram.
Mass = Mole× Molar mass
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 9 Solutions
Chemistry: Atoms First
Ch. 9.1 - Sports drinks typically contain sucrose...Ch. 9.1 - Prob. 1PPACh. 9.1 - Prob. 1PPBCh. 9.1 - Prob. 1PPCCh. 9.1 - Prob. 9.1.1SRCh. 9.1 - Prob. 9.1.2SRCh. 9.1 - Prob. 9.1.3SRCh. 9.2 - Classify each of the following compounds as...Ch. 9.2 - Prob. 2PPACh. 9.2 - Prob. 2PPB
Ch. 9.2 - Using Tables 9.2 and 9.3, identify a compound that...Ch. 9.2 - Prob. 9.3WECh. 9.2 - Prob. 3PPACh. 9.2 - Prob. 3PPBCh. 9.2 - Which diagram best represents the result when...Ch. 9.2 - Prob. 9.2.1SRCh. 9.2 - Prob. 9.2.2SRCh. 9.2 - Prob. 9.2.3SRCh. 9.2 - Prob. 9.2.4SRCh. 9.2 - Prob. 9.2.5SRCh. 9.3 - Prob. 9.4WECh. 9.3 - Prob. 4PPACh. 9.3 - Prob. 4PPBCh. 9.3 - Prob. 4PPCCh. 9.3 - Prob. 9.3.1SRCh. 9.3 - Prob. 9.3.2SRCh. 9.3 - Prob. 9.3.3SRCh. 9.3 - Prob. 9.3.4SRCh. 9.4 - Prob. 9.5WECh. 9.4 - Prob. 5PPACh. 9.4 - Prob. 5PPBCh. 9.4 - Write the balanced equation for the reaction...Ch. 9.4 - Prob. 9.6WECh. 9.4 - Using the activity series, predict which of the...Ch. 9.4 - Prob. 6PPBCh. 9.4 - Prob. 6PPCCh. 9.4 - Prob. 9.7WECh. 9.4 - Predict which of the following reactions will...Ch. 9.4 - Prob. 7PPBCh. 9.4 - Prob. 7PPCCh. 9.4 - Prob. 9.4.1SRCh. 9.4 - Prob. 9.4.2SRCh. 9.4 - Prob. 9.4.3SRCh. 9.4 - Prob. 9.4.4SRCh. 9.5 - Prob. 9.8WECh. 9.5 - Prob. 8PPACh. 9.5 - Prob. 8PPBCh. 9.5 - Prob. 8PPCCh. 9.5 - Prob. 9.9WECh. 9.5 - Prob. 9PPACh. 9.5 - Prob. 9PPBCh. 9.5 - Prob. 9PPCCh. 9.5 - Starting with a 2.0-M stock solution of...Ch. 9.5 - Starting with a 6.552-M stock solution of HNO3,...Ch. 9.5 - Five standard solutions of HBr are prepared by...Ch. 9.5 - Prob. 10PPCCh. 9.5 - Prob. 9.11WECh. 9.5 - Prob. 11PPACh. 9.5 - Prob. 11PPBCh. 9.5 - Prob. 11PPCCh. 9.5 - Prob. 9.12WECh. 9.5 - Calculate the hydronium ion concentration in a...Ch. 9.5 - Prob. 12PPBCh. 9.5 - Prob. 12PPCCh. 9.5 - Prob. 9.13WECh. 9.5 - Prob. 13PPACh. 9.5 - Prob. 13PPBCh. 9.5 - Prob. 13PPCCh. 9.5 - Prob. 9.5.1SRCh. 9.5 - Prob. 9.5.2SRCh. 9.5 - Prob. 9.5.3SRCh. 9.5 - Prob. 9.5.4SRCh. 9.5 - Prob. 9.5.5SRCh. 9.5 - Prob. 9.5.6SRCh. 9.6 - Prob. 9.14WECh. 9.6 - Prob. 14PPACh. 9.6 - Prob. 14PPBCh. 9.6 - Which diagram best represents the solution...Ch. 9.6 - Prob. 9.15WECh. 9.6 - Prob. 15PPACh. 9.6 - What volume (in mL) of a 0.2550 M NaOH solution...Ch. 9.6 - Prob. 15PPCCh. 9.6 - Prob. 9.16WECh. 9.6 - Prob. 16PPACh. 9.6 - Prob. 16PPBCh. 9.6 - Prob. 16PPCCh. 9.6 - Prob. 9.17WECh. 9.6 - Prob. 17PPACh. 9.6 - What is the molar mass of a diprotic acid if 30.5...Ch. 9.6 - Prob. 17PPCCh. 9.6 - Prob. 9.6.1SRCh. 9.6 - Prob. 9.6.2SRCh. 9.6 - Prob. 9.6.3SRCh. 9.6 - Prob. 9.6.4SRCh. 9 - Define solute, solvent, and solution by describing...Ch. 9 - What is the difference between a nonelectrolyte...Ch. 9 - Prob. 9.3QPCh. 9 - Prob. 9.4QPCh. 9 - Prob. 9.5QPCh. 9 - Prob. 9.6QPCh. 9 - You are given a water-soluble compound X. Describe...Ch. 9 - Prob. 9.8QPCh. 9 - Prob. 9.9QPCh. 9 - Prob. 9.10QPCh. 9 - Which of the following diagrams best represents...Ch. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Describe hydration. What properties of water...Ch. 9 - What is the difference between a molecular...Ch. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Which reaction is represented by the net ionic...Ch. 9 - Prob. 9.20QPCh. 9 - Characterize the following compounds as soluble or...Ch. 9 - Write ionic and net ionic equations for the...Ch. 9 - Write ionic and net ionic equations for the...Ch. 9 - Prob. 9.24QPCh. 9 - Which of the following processes will likely...Ch. 9 - List the general properties of acids and bases.Ch. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - What factors qualify a compound as a salt? Specify...Ch. 9 - Identify the following as a weak or strong acid or...Ch. 9 - Prob. 9.32QPCh. 9 - Prob. 9.33QPCh. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Prob. 9.37QPCh. 9 - Prob. 9.38QPCh. 9 - Describe how the activity series is organized, and...Ch. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - For the complete redox reactions represented here,...Ch. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Give the oxidation numbers for the underlined...Ch. 9 - Give the oxidation numbers for the underlined...Ch. 9 - Prob. 9.49QPCh. 9 - Prob. 9.50QPCh. 9 - Prob. 9.51QPCh. 9 - Prob. 9.52QPCh. 9 - Prob. 9.53QPCh. 9 - Prob. 9.54QPCh. 9 - Prob. 9.55QPCh. 9 - Which of the following would result in the actual...Ch. 9 - Why cant we prepare the solution by first filling...Ch. 9 - Prob. 9.3VCCh. 9 - Prob. 9.4VCCh. 9 - Prob. 9.56QPCh. 9 - Prob. 9.57QPCh. 9 - Prob. 9.58QPCh. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Prob. 9.62QPCh. 9 - Prob. 9.63QPCh. 9 - Prob. 9.64QPCh. 9 - Prob. 9.65QPCh. 9 - Prob. 9.66QPCh. 9 - Prob. 9.67QPCh. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Prob. 9.71QPCh. 9 - Prob. 9.72QPCh. 9 - Prob. 9.73QPCh. 9 - Prob. 9.74QPCh. 9 - Prob. 9.75QPCh. 9 - Prob. 9.76QPCh. 9 - Prob. 9.77QPCh. 9 - Prob. 9.78QPCh. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Prob. 9.81QPCh. 9 - Prob. 9.82QPCh. 9 - Complete the following table for a solution at...Ch. 9 - (a) What is the Na+ concentration in each of the...Ch. 9 - (a) Determine the chloride ion concentration in...Ch. 9 - Prob. 9.86QPCh. 9 - Determine the resulting nitrate ion concentration...Ch. 9 - Prob. 9.88QPCh. 9 - Absorbance values for five standard solutions of a...Ch. 9 - Which best represents the before-and-after...Ch. 9 - Prob. 9.91QPCh. 9 - Describe the basic steps involved in gravimetric...Ch. 9 - Explain why distilled water must be used in the...Ch. 9 - Describe the basic steps involved in an acid-base...Ch. 9 - Prob. 9.95QPCh. 9 - Prob. 9.96QPCh. 9 - Would the volume of a 0.10 M NaOH solution needed...Ch. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - The concentration of Cu2+ ions in the water (which...Ch. 9 - How many grams of NaCl are required to precipitate...Ch. 9 - Prob. 9.102QPCh. 9 - Prob. 9.103QPCh. 9 - Prob. 9.104QPCh. 9 - Prob. 9.105QPCh. 9 - Which of the following best represents the...Ch. 9 - Prob. 9.107QPCh. 9 - Prob. 9.108QPCh. 9 - Prob. 9.109QPCh. 9 - Prob. 9.110QPCh. 9 - Prob. 9.111QPCh. 9 - A 5.00 102 mL sample of 2.00 M HCl solution is...Ch. 9 - Calculate the volume of a 0.156 M CuSO4 solution...Ch. 9 - Prob. 9.114QPCh. 9 - Prob. 9.115QPCh. 9 - Prob. 9.116QPCh. 9 - Prob. 9.117QPCh. 9 - Prob. 9.118QPCh. 9 - Prob. 9.119QPCh. 9 - Prob. 9.120QPCh. 9 - Prob. 9.121QPCh. 9 - Prob. 9.122QPCh. 9 - Prob. 9.123QPCh. 9 - Prob. 9.124QPCh. 9 - Classify the following reactions according to the...Ch. 9 - Prob. 9.126QPCh. 9 - Prob. 9.127QPCh. 9 - Prob. 9.128QPCh. 9 - Prob. 9.129QPCh. 9 - Prob. 9.130QPCh. 9 - Prob. 9.131QPCh. 9 - Prob. 9.132QPCh. 9 - Prob. 9.133QPCh. 9 - Prob. 9.134QPCh. 9 - Prob. 9.135QPCh. 9 - Prob. 9.136QPCh. 9 - The concentration of lead ions (Pb2+) in a sample...Ch. 9 - Prob. 9.138QPCh. 9 - Prob. 9.139QPCh. 9 - Prob. 9.140QPCh. 9 - Prob. 9.141QPCh. 9 - Prob. 9.142QPCh. 9 - Prob. 9.143QPCh. 9 - The following are common household compounds: salt...Ch. 9 - Prob. 9.145QPCh. 9 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 9 - Prob. 9.147QPCh. 9 - Prob. 9.148QPCh. 9 - Acetylsalicylic acid (HC9H7O4) is a monoprotic...Ch. 9 - Prob. 9.150QPCh. 9 - Prob. 9.151QPCh. 9 - Prob. 9.152QPCh. 9 - Prob. 9.153QPCh. 9 - Prob. 9.154QPCh. 9 - Prob. 9.155QPCh. 9 - Prob. 9.156QPCh. 9 - Prob. 9.157QPCh. 9 - Prob. 9.158QPCh. 9 - Prob. 9.159QPCh. 9 - Prob. 9.160QPCh. 9 - Prob. 9.161QPCh. 9 - Prob. 9.162QPCh. 9 - Give a chemical explanation for each of the...Ch. 9 - Prob. 9.164QPCh. 9 - The following cycle of copper experiment is...Ch. 9 - Use the periodic table framework given here to...Ch. 9 - A 22.02-mL solution containing 1.615 g Mg(NO3)2 is...Ch. 9 - Because the acid-base and precipitation reactions...Ch. 9 - Prob. 9.1KSPCh. 9 - Prob. 9.2KSPCh. 9 - Prob. 9.3KSPCh. 9 - Prob. 9.4KSP
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