Chemistry: Atoms First
Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 9, Problem 9.165QP

The following “cycle of copper” experiment is performed in some general chemistry laboratories. The series of reactions starts with copper and ends with metallic copper. The steps are as follows: (1) A piece of copper wire of known mass is allowed to react with concentrated nitric acid [the products are copper(II) nitrate, nitrogen dioxide, and water]. (2) The copper (II) nitrate is treated with a sodium hydroxide solution to form copper(II) hydroxide precipitate. (3) On heating, copper(II) hydroxide decomposes to yield copper(II) oxide. (4) The copper(II) oxide is combined with concentrated sulfuric acid to yield copper(II) sulfate. (5) Copper(II) sulfate is treated with an excess of zinc metal to form metallic copper. (6) The remaining zinc metal is removed by treatment with hydrochloric acid, and metallic copper is filtered, dried, and weighed, (a) Write a balanced equation for each step and classify the reactions, (b) Assuming that a student started with 65.6 g of copper, calculate the theoretical yield at each step, (c) Considering the nature of the steps, comment on why it is possible to recover most of the copper used at the start.

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Chapter 9 Solutions

Chemistry: Atoms First

Ch. 9.2 - Using Tables 9.2 and 9.3, identify a compound that...Ch. 9.2 - Prob. 9.3WECh. 9.2 - Prob. 3PPACh. 9.2 - Prob. 3PPBCh. 9.2 - Which diagram best represents the result when...Ch. 9.2 - Prob. 9.2.1SRCh. 9.2 - Prob. 9.2.2SRCh. 9.2 - Prob. 9.2.3SRCh. 9.2 - Prob. 9.2.4SRCh. 9.2 - Prob. 9.2.5SRCh. 9.3 - Prob. 9.4WECh. 9.3 - Prob. 4PPACh. 9.3 - Prob. 4PPBCh. 9.3 - Prob. 4PPCCh. 9.3 - Prob. 9.3.1SRCh. 9.3 - Prob. 9.3.2SRCh. 9.3 - Prob. 9.3.3SRCh. 9.3 - Prob. 9.3.4SRCh. 9.4 - Prob. 9.5WECh. 9.4 - Prob. 5PPACh. 9.4 - Prob. 5PPBCh. 9.4 - Write the balanced equation for the reaction...Ch. 9.4 - Prob. 9.6WECh. 9.4 - Using the activity series, predict which of the...Ch. 9.4 - Prob. 6PPBCh. 9.4 - Prob. 6PPCCh. 9.4 - Prob. 9.7WECh. 9.4 - Predict which of the following reactions will...Ch. 9.4 - Prob. 7PPBCh. 9.4 - Prob. 7PPCCh. 9.4 - Prob. 9.4.1SRCh. 9.4 - Prob. 9.4.2SRCh. 9.4 - Prob. 9.4.3SRCh. 9.4 - Prob. 9.4.4SRCh. 9.5 - Prob. 9.8WECh. 9.5 - Prob. 8PPACh. 9.5 - Prob. 8PPBCh. 9.5 - Prob. 8PPCCh. 9.5 - Prob. 9.9WECh. 9.5 - Prob. 9PPACh. 9.5 - Prob. 9PPBCh. 9.5 - Prob. 9PPCCh. 9.5 - Starting with a 2.0-M stock solution of...Ch. 9.5 - Starting with a 6.552-M stock solution of HNO3,...Ch. 9.5 - Five standard solutions of HBr are prepared by...Ch. 9.5 - Prob. 10PPCCh. 9.5 - Prob. 9.11WECh. 9.5 - Prob. 11PPACh. 9.5 - Prob. 11PPBCh. 9.5 - Prob. 11PPCCh. 9.5 - Prob. 9.12WECh. 9.5 - Calculate the hydronium ion concentration in a...Ch. 9.5 - Prob. 12PPBCh. 9.5 - Prob. 12PPCCh. 9.5 - Prob. 9.13WECh. 9.5 - Prob. 13PPACh. 9.5 - Prob. 13PPBCh. 9.5 - Prob. 13PPCCh. 9.5 - Prob. 9.5.1SRCh. 9.5 - Prob. 9.5.2SRCh. 9.5 - Prob. 9.5.3SRCh. 9.5 - Prob. 9.5.4SRCh. 9.5 - Prob. 9.5.5SRCh. 9.5 - Prob. 9.5.6SRCh. 9.6 - Prob. 9.14WECh. 9.6 - Prob. 14PPACh. 9.6 - Prob. 14PPBCh. 9.6 - Which diagram best represents the solution...Ch. 9.6 - Prob. 9.15WECh. 9.6 - Prob. 15PPACh. 9.6 - What volume (in mL) of a 0.2550 M NaOH solution...Ch. 9.6 - Prob. 15PPCCh. 9.6 - Prob. 9.16WECh. 9.6 - Prob. 16PPACh. 9.6 - Prob. 16PPBCh. 9.6 - Prob. 16PPCCh. 9.6 - Prob. 9.17WECh. 9.6 - Prob. 17PPACh. 9.6 - What is the molar mass of a diprotic acid if 30.5...Ch. 9.6 - Prob. 17PPCCh. 9.6 - Prob. 9.6.1SRCh. 9.6 - Prob. 9.6.2SRCh. 9.6 - Prob. 9.6.3SRCh. 9.6 - Prob. 9.6.4SRCh. 9 - Define solute, solvent, and solution by describing...Ch. 9 - What is the difference between a nonelectrolyte...Ch. 9 - Prob. 9.3QPCh. 9 - Prob. 9.4QPCh. 9 - Prob. 9.5QPCh. 9 - Prob. 9.6QPCh. 9 - You are given a water-soluble compound X. Describe...Ch. 9 - Prob. 9.8QPCh. 9 - Prob. 9.9QPCh. 9 - Prob. 9.10QPCh. 9 - Which of the following diagrams best represents...Ch. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Describe hydration. What properties of water...Ch. 9 - What is the difference between a molecular...Ch. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Which reaction is represented by the net ionic...Ch. 9 - Prob. 9.20QPCh. 9 - Characterize the following compounds as soluble or...Ch. 9 - Write ionic and net ionic equations for the...Ch. 9 - Write ionic and net ionic equations for the...Ch. 9 - Prob. 9.24QPCh. 9 - Which of the following processes will likely...Ch. 9 - List the general properties of acids and bases.Ch. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - What factors qualify a compound as a salt? Specify...Ch. 9 - Identify the following as a weak or strong acid or...Ch. 9 - Prob. 9.32QPCh. 9 - Prob. 9.33QPCh. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Prob. 9.37QPCh. 9 - Prob. 9.38QPCh. 9 - Describe how the activity series is organized, and...Ch. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - For the complete redox reactions represented here,...Ch. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Give the oxidation numbers for the underlined...Ch. 9 - Give the oxidation numbers for the underlined...Ch. 9 - Prob. 9.49QPCh. 9 - Prob. 9.50QPCh. 9 - Prob. 9.51QPCh. 9 - Prob. 9.52QPCh. 9 - Prob. 9.53QPCh. 9 - Prob. 9.54QPCh. 9 - Prob. 9.55QPCh. 9 - Which of the following would result in the actual...Ch. 9 - Why cant we prepare the solution by first filling...Ch. 9 - Prob. 9.3VCCh. 9 - Prob. 9.4VCCh. 9 - Prob. 9.56QPCh. 9 - Prob. 9.57QPCh. 9 - Prob. 9.58QPCh. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Prob. 9.62QPCh. 9 - Prob. 9.63QPCh. 9 - Prob. 9.64QPCh. 9 - Prob. 9.65QPCh. 9 - Prob. 9.66QPCh. 9 - Prob. 9.67QPCh. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Prob. 9.71QPCh. 9 - Prob. 9.72QPCh. 9 - Prob. 9.73QPCh. 9 - Prob. 9.74QPCh. 9 - Prob. 9.75QPCh. 9 - Prob. 9.76QPCh. 9 - Prob. 9.77QPCh. 9 - Prob. 9.78QPCh. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Prob. 9.81QPCh. 9 - Prob. 9.82QPCh. 9 - Complete the following table for a solution at...Ch. 9 - (a) What is the Na+ concentration in each of the...Ch. 9 - (a) Determine the chloride ion concentration in...Ch. 9 - Prob. 9.86QPCh. 9 - Determine the resulting nitrate ion concentration...Ch. 9 - Prob. 9.88QPCh. 9 - Absorbance values for five standard solutions of a...Ch. 9 - Which best represents the before-and-after...Ch. 9 - Prob. 9.91QPCh. 9 - Describe the basic steps involved in gravimetric...Ch. 9 - Explain why distilled water must be used in the...Ch. 9 - Describe the basic steps involved in an acid-base...Ch. 9 - Prob. 9.95QPCh. 9 - Prob. 9.96QPCh. 9 - Would the volume of a 0.10 M NaOH solution needed...Ch. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - The concentration of Cu2+ ions in the water (which...Ch. 9 - How many grams of NaCl are required to precipitate...Ch. 9 - Prob. 9.102QPCh. 9 - Prob. 9.103QPCh. 9 - Prob. 9.104QPCh. 9 - Prob. 9.105QPCh. 9 - Which of the following best represents the...Ch. 9 - Prob. 9.107QPCh. 9 - Prob. 9.108QPCh. 9 - Prob. 9.109QPCh. 9 - Prob. 9.110QPCh. 9 - Prob. 9.111QPCh. 9 - A 5.00 102 mL sample of 2.00 M HCl solution is...Ch. 9 - Calculate the volume of a 0.156 M CuSO4 solution...Ch. 9 - Prob. 9.114QPCh. 9 - Prob. 9.115QPCh. 9 - Prob. 9.116QPCh. 9 - Prob. 9.117QPCh. 9 - Prob. 9.118QPCh. 9 - Prob. 9.119QPCh. 9 - Prob. 9.120QPCh. 9 - Prob. 9.121QPCh. 9 - Prob. 9.122QPCh. 9 - Prob. 9.123QPCh. 9 - Prob. 9.124QPCh. 9 - Classify the following reactions according to the...Ch. 9 - Prob. 9.126QPCh. 9 - Prob. 9.127QPCh. 9 - Prob. 9.128QPCh. 9 - Prob. 9.129QPCh. 9 - Prob. 9.130QPCh. 9 - Prob. 9.131QPCh. 9 - Prob. 9.132QPCh. 9 - Prob. 9.133QPCh. 9 - Prob. 9.134QPCh. 9 - Prob. 9.135QPCh. 9 - Prob. 9.136QPCh. 9 - The concentration of lead ions (Pb2+) in a sample...Ch. 9 - Prob. 9.138QPCh. 9 - Prob. 9.139QPCh. 9 - Prob. 9.140QPCh. 9 - Prob. 9.141QPCh. 9 - Prob. 9.142QPCh. 9 - Prob. 9.143QPCh. 9 - The following are common household compounds: salt...Ch. 9 - Prob. 9.145QPCh. 9 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 9 - Prob. 9.147QPCh. 9 - Prob. 9.148QPCh. 9 - Acetylsalicylic acid (HC9H7O4) is a monoprotic...Ch. 9 - Prob. 9.150QPCh. 9 - Prob. 9.151QPCh. 9 - Prob. 9.152QPCh. 9 - Prob. 9.153QPCh. 9 - Prob. 9.154QPCh. 9 - Prob. 9.155QPCh. 9 - Prob. 9.156QPCh. 9 - Prob. 9.157QPCh. 9 - Prob. 9.158QPCh. 9 - Prob. 9.159QPCh. 9 - Prob. 9.160QPCh. 9 - Prob. 9.161QPCh. 9 - Prob. 9.162QPCh. 9 - Give a chemical explanation for each of the...Ch. 9 - Prob. 9.164QPCh. 9 - The following cycle of copper experiment is...Ch. 9 - Use the periodic table framework given here to...Ch. 9 - A 22.02-mL solution containing 1.615 g Mg(NO3)2 is...Ch. 9 - Because the acid-base and precipitation reactions...Ch. 9 - Prob. 9.1KSPCh. 9 - Prob. 9.2KSPCh. 9 - Prob. 9.3KSPCh. 9 - Prob. 9.4KSP
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