(a) Interpretation: The feed rates of the SO 2 and air feed streams and the extent of reaction, e should be calculated. Concept Introduction The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Question

3. Nitric oxide is produced in the body by several different enzymes and acts as a signal that controls blood pressure, long-term memory, and other critical functions. The major route for removing NO from biological fluids is via reaction with O2 to give NO₂ 2NO(g) + O2(g) → 2NO2(g) The following table lists kinetics data for the reaction of NO with O2 at 25°C: Experiment 1 [NO] (M) 0.0235 2 0.0235 3 0.0470 4 0.0470 (a) Determine the rate law for the reaction (b) calculate the rate constant. [02]0 (M) Initial Rate (M/s) 0.0125 7.98 × 10-3 0.0250 15.9 × 10-3 0.0125 32.0 × 10-3 0.0250 63.5 x 10-3 5:32

Answer 1

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

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3. Nitric oxide is produced in the body by several different enzymes and acts as a signal that controls blood pressure, long-term memory, and other critical functions. The major route for removing NO from biological fluids is via reaction with O2 to give NO₂ 2NO(g) + O2(g) → 2NO2(g) The following table lists kinetics data for the reaction of NO with O2 at 25°C: Experiment 1 [NO] (M) 0.0235 2 0.0235 3 0.0470 4 0.0470 (a) Determine the rate law for the reaction (b) calculate the rate constant. [02]0 (M) Initial Rate (M/s) 0.0125 7.98 × 10-3 0.0250 15.9 × 10-3 0.0125 32.0 × 10-3 0.0250 63.5 x 10-3 5:32

A closed system of 122 moles of an ideal gas with constant-pressure heat capacity of cp = 2.5R expands isobarically from 52°C and 4.9 bar to 137°C, with a thermodynamic efficiency of 0.74. How much total work is involved in this process? Please report your answer to the nearest whole kJ and don't forget the sign: "-" if the work is negative, no sign if the work is positive.

Liquid toluene at 20°C is reversibly and isothermally compressed from 2.94 bar to 7.7 bar. What is the specific work, in J/kg, required to accomplish this? Some properties of liquid toluene at 20°C: β = 1.05 x 10-3 ºC-1 , κ = 8.96 x 10-5 bar-1 , V = 1154 cm3 kg-1. Please report your answer to 3 SF. Be very, very careful of units!

Answer 2

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

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Answer 3

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

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Answer 4

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

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Answer 5

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

Answer 6

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Answer 7

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Answer 9

Interpretation Introduction

(b)

Interpretation:

Calculate the standard heat of the SO₂ oxidation reaction in kJ. Taking molecular species at 25? as references, an inlet-outlet enthalpy table should be prepared and filled in. Write an energy balance to calculate the necessary rate of heat transfer (kW) from the reactor to the cooling water.

Concept introduction:

The standard heat of formation will be helpful to solve the problem as:

ΔHr0=ΔHf0(product)−ΔHf0(reactant)

Answer 10

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

Answer 14

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Answer 15

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Answer 25

Ch. 9 - The standard heat of the reaction...Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - The standard heat of the reaction...Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - The standard heat of combustion of gaseous ethane...Ch. 9 - The standard heat of combustion (AH°) of liquid...

(a) Interpretation: The feed rates of the SO 2 and air feed streams and the extent of reaction, e should be calculated. Concept Introduction The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Solution Summary: The author explains the feed rates of SO 2 and air feed streams and the extent of reaction, e. The basic feed is 1 mol Heptanes taken at 400?

Concept explainers

(a)

Interpretation:

The feed rates of the SO₂ and air feed streams and the extent of reaction, e should be calculated.

Concept Introduction

The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

(c)

Interpretation:

Calculate the minimum flow rate of heat transfer (kW) from the reactor to the cooling water.

(d)

Interpretation:

The result if element species is taken into calculation in part (b) should be stated.

Chapter 9 Solutions

(a) Interpretation: The feed rates of the SO 2 and air feed streams and the extent of reaction, e should be calculated. Concept Introduction The feed rates and extent of reactions can be better explained on the basis of flow chart formed from the given data.

Solution Summary: The author explains the feed rates of SO 2 and air feed streams and the extent of reaction, e. The basic feed is 1 mol Heptanes taken at 400?

Concept explainers