Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 9, Problem 3E
Why should you roll or belly-crawl rather than walk across a thinly-frozen pond?
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Question
Suggest a mechanism for the following reactions. Each will require multiple
types of concerted pericyclic reactions (cycloaddition, electrocyclic, and
sigmatropic. Classify each reaction type.
CN
a.
NC
180 °C
Don't used Ai solution and don't used hand raiting
Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Chapter 9 Solutions
Chemistry (OER)
Ch. 9 - Why are sharp knives more effective than dull...Ch. 9 - Why do some small bridges have weight limits that...Ch. 9 - Why should you roll or belly-crawl rather than...Ch. 9 - A typical barometric pressure in Redding....Ch. 9 - A typical barometric pressure in Denver, Colorado,...Ch. 9 - A typical barometric pressure in Kansas City is...Ch. 9 - Canadian tire pressure gauges are marked in units...Ch. 9 - Dining the Viking landings on Mars, the...Ch. 9 - The pressure of the atmosphere on the surface of...Ch. 9 - A medical laboratory catalog describes the...
Ch. 9 - Consider this scenario and answer the following...Ch. 9 - Why is it necessary to use a nonvolatile liquid in...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas is measured with...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas ¡s measured a sea...Ch. 9 - How would the use of a volatile liquid affect the...Ch. 9 - Sometimes leaving a bicycle in the sun on a hot...Ch. 9 - Explain how the volume of the bubbles exhausted by...Ch. 9 - One way to state Boyle’s law is All other things...Ch. 9 - An alternate way to state Avogadro’s law is A1l...Ch. 9 - How would the graph in Figure 9.12 change if the...Ch. 9 - How would the graph in Figure 9.13 change if the...Ch. 9 - In addition to the data found in Figure 9.13, what...Ch. 9 - Determine the volume of 1 mol of CH4 gas at 150 K...Ch. 9 - Determine the pressure of the gas in the syringe...Ch. 9 - A spray can is used until it is empty except for...Ch. 9 - What is the temperature of an 11.2-L sample of...Ch. 9 - À 2.50-L volume of hydrogen measured at —196 C is...Ch. 9 - A balloon inflated with three breaths of air has a...Ch. 9 - A weather balloon contains 8.80 moles of helium at...Ch. 9 - The volume of an automobile air bag was 66.8 L...Ch. 9 - How many moles of gaseous boron trifluoride, BF3,...Ch. 9 - Iodine, I2, is a solid at room temperature but...Ch. 9 - How many grams of gas are present in each of the...Ch. 9 - A high altitude balloon is filled with 1041104 L...Ch. 9 - A cylinder of medical oxygen has a volume of 3S.4...Ch. 9 - A large scuba tank (Figure 9.16) with a volume of...Ch. 9 - A 20.0-L cylinder containing 11.34 kg of butane,...Ch. 9 - While resting, the average 70-kg human male...Ch. 9 - For a given amount of gas showing ideal behavior,...Ch. 9 - A liter of methane gas, CH4, at STP contains more...Ch. 9 - The effect of chlorofluorocarbons (such as CCl2F2)...Ch. 9 - As 1 g of (lie radioactive element radium decays...Ch. 9 - A balloon that is 100.21 L at 21 C and 0.981 atm...Ch. 9 - If the temperature of a fixed amount of a gas is...Ch. 9 - If the volume of a fixed amount of a gas is...Ch. 9 - What is the density of laughing gas, dinitrogen...Ch. 9 - Calculate the density of Freon 12, CF2Cl2, at 30.0...Ch. 9 - Which is denser at the same temperature and...Ch. 9 - A cylinder of O2(g) used in breathing by emphysema...Ch. 9 - What is the molar mass of a gas if 0.0494 g of the...Ch. 9 - What is the molar mass of a gas if 0.281 g of the...Ch. 9 - How could you show experimentally that the...Ch. 9 - The density of a certain gaseous fluoride of...Ch. 9 - Consider this question: What is the molecular...Ch. 9 - A 36.0—L cylinder of a gas used for calibration of...Ch. 9 - A cylinder of a gas mixture used for calibration...Ch. 9 - A sample of gas isolated from unrefined petroleum...Ch. 9 - A mixture of 0.200 g of 1.00 g of and 0.820 g of...Ch. 9 - Most mixtures of hydrogen gas with oxygen gas are...Ch. 9 - A commercial mercury vapor analyzer can detect in...Ch. 9 - A sample of carbon monoxide was collected over...Ch. 9 - In an experiment in a general chemistry...Ch. 9 - Joseph Priestley first prepared pure oxygen by...Ch. 9 - Cavendish prepared hydrogen in 176G by the novel...Ch. 9 - The chlorofluorocarbon CCl2F2 can be recycled into...Ch. 9 - Automobile air bags are inflated with nitrogen...Ch. 9 - Lime, CaO, is produced by heating calcium...Ch. 9 - Before small batteries were available, carbide...Ch. 9 - Calculate the volume of oxygen required to burn...Ch. 9 - What volume of O2 at STP is required to oxidize...Ch. 9 - Consider the following questions: (a) What is the...Ch. 9 - Methanol, CH3OH, is produced industrially by the...Ch. 9 - What volume of oxygen a 423.0 K and a pressure of...Ch. 9 - A 230-L sample of a colorless gas at STP...Ch. 9 - Ethanol, C2H5OH, is produced industrially from...Ch. 9 - One molecule of hemoglobin will combine with four...Ch. 9 - A sample of a compound of xenon and fluorine was...Ch. 9 - One method of analyzing amino acids is the van...Ch. 9 - A balloon filled with helium gas is found to take...Ch. 9 - Explain why the numbers of molecules are not...Ch. 9 - Starting with the definition of rate of effusion...Ch. 9 - Heavy water, D2O (molar mass = 20.03 g mol-1). can...Ch. 9 - Which of the following gases diffuse more slowly...Ch. 9 - During the discussion of gaseous diffusion for...Ch. 9 - Calculate the relative rate of diffusion of 1H2...Ch. 9 - A gas of unknown identity diffuses at a rate of...Ch. 9 - When two cotton plugs. one moistened with ammonia...Ch. 9 - Using the postulates of the kinetic molecular...Ch. 9 - Can the speed of a given molecule in a gas double...Ch. 9 - Describe what happens o the average kinetic energy...Ch. 9 - The distribution of molecular velocities in a...Ch. 9 - What is the ratio of the average kinetic energy of...Ch. 9 - A 1-L sample of CO initially at STP is heated to...Ch. 9 - The root mean square speed of H2, molecules at 25...Ch. 9 - Answer the following questions: (a) Is the...Ch. 9 - Show that the ratio of the rate of diffusion of...Ch. 9 - Graphs showing the behavior of several different...Ch. 9 - Explain why the plot of PV for CO2 differs from...Ch. 9 - Under which of the following sets of conditions...Ch. 9 - Describe the factors responsible for the deviation...Ch. 9 - For which of the following gases should the...Ch. 9 - A 0.245-L flask contains 0.467 mol CO2 at 159 C....Ch. 9 - Answer the following questions: (a) If XX behaved...
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