Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 9, Problem 21E
An alternate way to state
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How is the resonance structure formed to make the following reaction product. Please hand draw the arrows showing how the electrons move to the correct position. Do not use an AI answer. Please draw it yourself or don't bother.
Part II Calculate λ max of the following compounds using wood ward- Fiecer rules
a)
b)
c)
d)
e)
OH
OH
dissolved in dioxane
Br
Br
dissolved in methanol.
NH₂
OCH 3
OH
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Chapter 9 Solutions
Chemistry (OER)
Ch. 9 - Why are sharp knives more effective than dull...Ch. 9 - Why do some small bridges have weight limits that...Ch. 9 - Why should you roll or belly-crawl rather than...Ch. 9 - A typical barometric pressure in Redding....Ch. 9 - A typical barometric pressure in Denver, Colorado,...Ch. 9 - A typical barometric pressure in Kansas City is...Ch. 9 - Canadian tire pressure gauges are marked in units...Ch. 9 - Dining the Viking landings on Mars, the...Ch. 9 - The pressure of the atmosphere on the surface of...Ch. 9 - A medical laboratory catalog describes the...
Ch. 9 - Consider this scenario and answer the following...Ch. 9 - Why is it necessary to use a nonvolatile liquid in...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas is measured with...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas ¡s measured a sea...Ch. 9 - How would the use of a volatile liquid affect the...Ch. 9 - Sometimes leaving a bicycle in the sun on a hot...Ch. 9 - Explain how the volume of the bubbles exhausted by...Ch. 9 - One way to state Boyle’s law is All other things...Ch. 9 - An alternate way to state Avogadro’s law is A1l...Ch. 9 - How would the graph in Figure 9.12 change if the...Ch. 9 - How would the graph in Figure 9.13 change if the...Ch. 9 - In addition to the data found in Figure 9.13, what...Ch. 9 - Determine the volume of 1 mol of CH4 gas at 150 K...Ch. 9 - Determine the pressure of the gas in the syringe...Ch. 9 - A spray can is used until it is empty except for...Ch. 9 - What is the temperature of an 11.2-L sample of...Ch. 9 - À 2.50-L volume of hydrogen measured at —196 C is...Ch. 9 - A balloon inflated with three breaths of air has a...Ch. 9 - A weather balloon contains 8.80 moles of helium at...Ch. 9 - The volume of an automobile air bag was 66.8 L...Ch. 9 - How many moles of gaseous boron trifluoride, BF3,...Ch. 9 - Iodine, I2, is a solid at room temperature but...Ch. 9 - How many grams of gas are present in each of the...Ch. 9 - A high altitude balloon is filled with 1041104 L...Ch. 9 - A cylinder of medical oxygen has a volume of 3S.4...Ch. 9 - A large scuba tank (Figure 9.16) with a volume of...Ch. 9 - A 20.0-L cylinder containing 11.34 kg of butane,...Ch. 9 - While resting, the average 70-kg human male...Ch. 9 - For a given amount of gas showing ideal behavior,...Ch. 9 - A liter of methane gas, CH4, at STP contains more...Ch. 9 - The effect of chlorofluorocarbons (such as CCl2F2)...Ch. 9 - As 1 g of (lie radioactive element radium decays...Ch. 9 - A balloon that is 100.21 L at 21 C and 0.981 atm...Ch. 9 - If the temperature of a fixed amount of a gas is...Ch. 9 - If the volume of a fixed amount of a gas is...Ch. 9 - What is the density of laughing gas, dinitrogen...Ch. 9 - Calculate the density of Freon 12, CF2Cl2, at 30.0...Ch. 9 - Which is denser at the same temperature and...Ch. 9 - A cylinder of O2(g) used in breathing by emphysema...Ch. 9 - What is the molar mass of a gas if 0.0494 g of the...Ch. 9 - What is the molar mass of a gas if 0.281 g of the...Ch. 9 - How could you show experimentally that the...Ch. 9 - The density of a certain gaseous fluoride of...Ch. 9 - Consider this question: What is the molecular...Ch. 9 - A 36.0—L cylinder of a gas used for calibration of...Ch. 9 - A cylinder of a gas mixture used for calibration...Ch. 9 - A sample of gas isolated from unrefined petroleum...Ch. 9 - A mixture of 0.200 g of 1.00 g of and 0.820 g of...Ch. 9 - Most mixtures of hydrogen gas with oxygen gas are...Ch. 9 - A commercial mercury vapor analyzer can detect in...Ch. 9 - A sample of carbon monoxide was collected over...Ch. 9 - In an experiment in a general chemistry...Ch. 9 - Joseph Priestley first prepared pure oxygen by...Ch. 9 - Cavendish prepared hydrogen in 176G by the novel...Ch. 9 - The chlorofluorocarbon CCl2F2 can be recycled into...Ch. 9 - Automobile air bags are inflated with nitrogen...Ch. 9 - Lime, CaO, is produced by heating calcium...Ch. 9 - Before small batteries were available, carbide...Ch. 9 - Calculate the volume of oxygen required to burn...Ch. 9 - What volume of O2 at STP is required to oxidize...Ch. 9 - Consider the following questions: (a) What is the...Ch. 9 - Methanol, CH3OH, is produced industrially by the...Ch. 9 - What volume of oxygen a 423.0 K and a pressure of...Ch. 9 - A 230-L sample of a colorless gas at STP...Ch. 9 - Ethanol, C2H5OH, is produced industrially from...Ch. 9 - One molecule of hemoglobin will combine with four...Ch. 9 - A sample of a compound of xenon and fluorine was...Ch. 9 - One method of analyzing amino acids is the van...Ch. 9 - A balloon filled with helium gas is found to take...Ch. 9 - Explain why the numbers of molecules are not...Ch. 9 - Starting with the definition of rate of effusion...Ch. 9 - Heavy water, D2O (molar mass = 20.03 g mol-1). can...Ch. 9 - Which of the following gases diffuse more slowly...Ch. 9 - During the discussion of gaseous diffusion for...Ch. 9 - Calculate the relative rate of diffusion of 1H2...Ch. 9 - A gas of unknown identity diffuses at a rate of...Ch. 9 - When two cotton plugs. one moistened with ammonia...Ch. 9 - Using the postulates of the kinetic molecular...Ch. 9 - Can the speed of a given molecule in a gas double...Ch. 9 - Describe what happens o the average kinetic energy...Ch. 9 - The distribution of molecular velocities in a...Ch. 9 - What is the ratio of the average kinetic energy of...Ch. 9 - A 1-L sample of CO initially at STP is heated to...Ch. 9 - The root mean square speed of H2, molecules at 25...Ch. 9 - Answer the following questions: (a) Is the...Ch. 9 - Show that the ratio of the rate of diffusion of...Ch. 9 - Graphs showing the behavior of several different...Ch. 9 - Explain why the plot of PV for CO2 differs from...Ch. 9 - Under which of the following sets of conditions...Ch. 9 - Describe the factors responsible for the deviation...Ch. 9 - For which of the following gases should the...Ch. 9 - A 0.245-L flask contains 0.467 mol CO2 at 159 C....Ch. 9 - Answer the following questions: (a) If XX behaved...
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- Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.arrow_forwardPart II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1arrow_forwardAE>AE₁ (Y/N) AE=AE₁ (Y/N) AEarrow_forwardTreatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br Aarrow_forwardCorrectly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν Harrow_forwardHow is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.arrow_forwardPart VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?arrow_forwardDon't used Ai solutionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward↑ 0 Quiz List - RCC430M_RU05 X Aktiv Learning App × Qdraw resonance structure ×Q draw resonance structure xb My Questions | bartleby ×+ https://app.aktiv.com Draw a resonance structure of pyrrole that has the same number of pi bonds as the original structure. Include all lone pairs in your structure. + N H a 5 19°F Cloudy Q Search Problem 12 of 15 Atoms, Bonds and Rings Charges and Lone Pairs myhp हजु Undo Reset Remove Done Submit Drag To Pan 2:15 PM 1/25/2025arrow_forwardDon't used hand raitingarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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