Principles of Chemistry: A Molecular Approach (3rd Edition)
Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 9, Problem 25E
Interpretation Introduction

Interpretation:

Using formal charges, the better of the two given structures is to be determined.

Concept introduction: A formal charge is the charge assigned to an atom in a molecule. It is assumed that electrons in all bonds are shared equally between atoms regardless of relative electronegativity.
The formal charge on an atom is calculated by the formula,

    Formalcharge=(Valenceelectrons[Lonepairelectrons+ Bondingelectrons 2])

To determine: Using formal charges, the better of the two given structures.

Blurred answer
Students have asked these similar questions
Please help with number 6 I got a negative number could that be right?
1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.
Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.

Chapter 9 Solutions

Principles of Chemistry: A Molecular Approach (3rd Edition)

Ch. 9 - Prob. 9.9PCh. 9 - Write the Lewis structure for XeF4.Ch. 9 - Prob. 9.10MPCh. 9 - Prob. 9.11PCh. 9 - Prob. 9.11MPCh. 9 - Prob. 1SAQCh. 9 - Prob. 2SAQCh. 9 - Prob. 3SAQCh. 9 - Prob. 4SAQCh. 9 - Prob. 5SAQCh. 9 - Prob. 6SAQCh. 9 - Prob. 7SAQCh. 9 - Prob. 8SAQCh. 9 - Prob. 9SAQCh. 9 - Prob. 10SAQCh. 9 - Prob. 11SAQCh. 9 - Prob. 12SAQCh. 9 - Use formal charge to choose the best Lewis...Ch. 9 - Use bond energies to determine Hrxnfor this...Ch. 9 - Prob. 15SAQCh. 9 - Prob. 1ECh. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Prob. 6ECh. 9 - Prob. 7ECh. 9 - Prob. 8ECh. 9 - Explain the trend in the lattice energies of the...Ch. 9 - Prob. 10ECh. 9 - The lattice enerqy of CsF is -744 kJ/mol, whereas...Ch. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Prob. 14ECh. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - Draw the Lewis structure for CO with an arrow...Ch. 9 - Prob. 20ECh. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Prob. 23ECh. 9 - 24. Write the Lewis structure that obeys the...Ch. 9 - Prob. 25ECh. 9 - Use formal charge to determine which of the two...Ch. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Prob. 30ECh. 9 - Prob. 31ECh. 9 - What are the formal charges of the atoms shown in...Ch. 9 - Write the Lewis structure for each molecule. a....Ch. 9 - Prob. 34ECh. 9 - Prob. 35ECh. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - Consider these three compounds: HCCH, H2CCH2...Ch. 9 - Prob. 40ECh. 9 - Prob. 41ECh. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Prob. 44ECh. 9 - Prob. 45ECh. 9 - Prob. 46ECh. 9 - Prob. 47ECh. 9 - Amino acids are the building blocks of proteins....Ch. 9 - Prob. 49ECh. 9 - Prob. 50ECh. 9 - Prob. 51ECh. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58ECh. 9 - Prob. 59ECh. 9 - Prob. 60ECh. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Calculate Hrxn for the combustion of octane...Ch. 9 - 65. Draw the Lewis structure for each compound. a....Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - Prob. 70ECh. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Prob. 73ECh. 9 - Prob. 74ECh. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - Prob. 82ECh. 9 - Prob. 83E
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY