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Concept explainers
Interpretation:
The enthalpy of the given reaction using bond enthalpies is to be calculated.
Concept introduction: Bond energy or bond enthalpy is the amount of energy required to break one mole of bonds. Breaking of bonds is an endothermic reaction because energy is always absorbed in the process and its value is always positive. Formation of bonds is an exothermic reaction because energy is always released in the process and its value is always negative.
The enthalpy of a reaction is the change in enthalpy of a system, when reactants change into products. It is denoted by
The value of
To determine: The enthalpy of reaction using bond enthalpies.
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Chapter 9 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
- 12. Choose the best diene and dienophile pair that would react the fastest. CN CN CO₂Et -CO₂Et .CO₂Et H3CO CO₂Et A B C D E Farrow_forward(6 pts - 2 pts each part) Although we focused our discussion on hydrogen light emission, all elements have distinctive emission spectra. Sodium (Na) is famous for its spectrum being dominated by two yellow emission lines at 589.0 and 589.6 nm, respectively. These lines result from electrons relaxing to the 3s subshell. a. What is the photon energy (in J) for one of these emission lines? Show your work. b. To what electronic transition in hydrogen is this photon energy closest to? Justify your answer-you shouldn't need to do numerical calculations. c. Consider the 3s subshell energy for Na - use 0 eV as the reference point for n=∞. What is the energy of the subshell that the electron relaxes from? Choose the same emission line that you did for part (a) and show your work.arrow_forwardNonearrow_forward
- (9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception to the general ionization energy (IE) trend. For the two elements involved, answer the following questions. Be sure to cite sources for all physical data that you use. a. (2 pts) Identify the two elements and write their electronic configurations. b. (2 pts) Based on their configurations, propose a reason for the IE trend exception. c. (5 pts) Calculate effective nuclear charges for the last electron in each element and the Allred-Rochow electronegativity values for the two elements. Can any of these values explain the IE trend exception? Explain how (not) - include a description of how IE relates to electronegativity.arrow_forwardPlease explain thoroughly and provide steps to draw.arrow_forwardAs you can see in the picture, the instrument uses a Xe source. Given that the instrument is capable of measuring from 200-800nm, if Xe was not used, what other source(s) could be used? Refer to figure 7-3. How many monochrometers does this instrument have? Why? Trace the light as it goes from the Xenon lamp all the way to the circle just slightly to the right and a little bit down from S4. What do you think that circle is? In class we talked about many types of these, which kind do you think this one is for a fluorimeter? Why? Explain. What is/are some strategy(ies) that this instrument has for dealing with noise that you see present in the optics diagram? Why does a fluorescence cuvette have to be clear on four sides?arrow_forward
- Provide steps and thoroughly solve.arrow_forwardNonearrow_forwardDevise a synthesis to prepare 4-tert-butyl-2-nitrotoluene from toluene. Complete the following reaction scheme. Part 1 of 4 Step 1 Step 2 A B Draw the structure for compound B, 4-tert-butyl-2-nitrotoluene. Click and drag to start drawing a structure. 'O Х ப:arrow_forward
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