Chapter 8.14, Problem 35PTS

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

• Hydroboration-oxidation reaction: In this reaction, reagent is borane followed by hydrogen peroxide and base NaOH. Addition of water molecule across the double bond of alkene is known as hydroboration-oxidation reaction. This reaction gives anti-Markovnikov’s addition product.
• Hydro halogenation: Addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction.
• Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
• Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

To find: the reagent for the given transformation.