Product should be predicted for the given reaction conditions. Concept introduction: Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid. In this reaction, intermediate is three membered cyclic oxonium ion ( epoxide formation), this cyclic strain will be revealed by the attack of nucleophile (water) molecule. Instead of water, some other nucleophiles also can attack and give anti-products. To find: the major product formed for given alkene while treated with peroxy acids followed by aqueous ethanol.

Question

Want to see the full answer?

Answer 1

Question

Chapter 8.10, Problem 25ATS

(a)

Interpretation Introduction

Interpretation:

Product should be predicted for the given reaction conditions.

Concept introduction:

Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation.

This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

In this reaction, intermediate is three membered cyclic oxonium ion (epoxide formation), this cyclic strain will be revealed by the attack of nucleophile (water) molecule.

Instead of water, some other nucleophiles also can attack and give anti-products.

To find: the major product formed for given alkene while treated with peroxy acids followed by aqueous ethanol.

(b)

Interpretation Introduction

Interpretation:

Product should be predicted for the given reaction conditions.

Concept introduction:

Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation.

This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

In this reaction, intermediate is three membered cyclic oxonium ion (epoxide formation), this cyclic strain will be revealed by the attack of nucleophile (water) molecule.

Instead of water, some other nucleophiles also can attack and give anti-products.

To find: the major product formed for given epoxide while treated with phenol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling point, choose 2 next to the substance with the next highest boiling point, and so on. substance C D chemical symbol, chemical formula or Lewis structure. CH,-N-CH, CH, H H 10: H C-C-H H H H Cale H 10: H-C-C-N-CH, Bri CH, boiling point (C) Сен (C) B (Choose

Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!

Q1: Answer the questions for the reaction below: ..!! Br OH a) Predict the product(s) of the reaction. b) Is the substrate optically active? Are the product(s) optically active as a mix? c) Draw the curved arrow mechanism for the reaction. d) What happens to the SN1 reaction rate in each of these instances: 1. Change the substrate to Br "CI 2. Change the substrate to 3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF 4. Increase the substrate concentration by 3-fold.