The products of acid-catalysed hydration and oxymercuration-demercuration of given reactants have to be identified. Concept Introduction: Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov’s addition. An acid-catalysed hydration is shown below. Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides. Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

Question

What are the IUPAC Names of all the compounds in the picture?

Answer 1

Question

Chapter 8.6, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The products of acid-catalysed hydration and oxymercuration-demercuration of given reactants have to be identified.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov’s addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

(b)

Interpretation Introduction

Interpretation:

The products of acid-catalysed hydration and oxymercuration-demercuration of given reactants have to be identified.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov’s addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

(c)

Interpretation Introduction

Interpretation:

The products of acid-catalysed hydration and oxymercuration-demercuration of given reactants have to be identified.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov’s addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

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