The major product obtained in the given reaction has to be identified. Concept Introduction: Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides. Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 1

Question

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)

Answer 2

Question

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 3

Question

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 4

Question

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 5

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 6

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 7

Chapter 8.4, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product obtained in the given reaction has to be identified.

Concept Introduction:

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: In the presence of per acid an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 8.4 - Prob. 1CC Ch. 8.4 - Prob. 2CC Ch. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTS Ch. 8.4 - Prob. 4ATS Ch. 8.4 - Prob. 5CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 6PTS Ch. 8.5 - Prob. 8CC Ch. 8.5 - Prob. 9CC

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