ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
4th Edition
ISBN: 9781119249214
Author: FELDER
Publisher: INTER WILE
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Chapter 8, Problem 8.96P
Interpretation Introduction
(a)
Interpretation:
Use Table B.11 to determine the specific enthalpy (
Concept introduction:
Interpretation Introduction
(b)
Interpretation:
Determine the specific enthalpy (
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b) Construct an enthalpy cycle and calculate the enthalpy of combustion in each case
using the above data.
3. Given the following data: AH(CH4) = -74.8 kJmol-¹, AH(CH3CI) = -134.5 kJmol-¹,
AH (HCI) = -92.3 kJmol-¹;
Construct an enthalpy cycle and calculate H for the reaction CH4(g) + Cl2(g)
CH3CI(g) + HCl(g)
4. Given the data:
4NH3(g) + 302(g) 0 2N2(g) + 6H2O(1), AH = -1530kJmol-1
H2(g) + 1/2O2(g) □ H₂O(1), AH = -288 kJmol-¹
Construct an enthalpy cycle and calculate the enthalpy of formation of ammonia.
i need solution of all parts . please
Calculate the standard enthalpy (kJ) change of the preparation of nitric acid below:
4NH3(g) + 502g) ==>
4NO(g) + 6H2O(3)
if AH°f = -45.9, O, 90.3 and - 241.8 KJ for NH3(2), O2(g), NO(3) and H20(g) respectively
906
-90.6
90.6
-906
Chapter 8 Solutions
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
Ch. 8 - 8.1. The specific internal energy of formaldehyde...Ch. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.5PCh. 8 - 8.6. Table B.7 of Appendix B gives the following...Ch. 8 - Prob. 8.7PCh. 8 - Two formulas for the heat capacity of CO are given...Ch. 8 - 8.9. Table B.2 lists values of the heat capacity...Ch. 8 - Prob. 8.10P
Ch. 8 - Chlorine gas is to be heated front 120°C and 1 atm...Ch. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Use the enthalpy function of APEx to calculate...Ch. 8 - A stream of carbon monoxide flowing at 300 kg/min...Ch. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Calculate the heat transfer (kJ) required to cool...Ch. 8 - Twenty liters of liquid n-propyl benzoate...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - A fuel gas containing 95 mole% methane and the...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Ever wonder why espresso costs much more per cup...Ch. 8 - Prob. 8.31PCh. 8 - Saturated steam at 300°C is used to heat a...Ch. 8 - Pure ethane is burned completely with preheated...Ch. 8 - An adiabatic membrane separation unit is used to...Ch. 8 - A gas containing water vapor has a dry-basis...Ch. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - In the manufacture of nitric acid, ammonia and...Ch. 8 - A natural gas containing 95 mole% methane and the...Ch. 8 - The heat capacity at constant pressure of a gas is...Ch. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Calculate the heat of vaporization of water...Ch. 8 - Polyvinylpyrrolidone (PVP) is a polymer product...Ch. 8 - Benzene vapor at 480°C is cooled and converted to...Ch. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - A stream of pure cyclopentane vapor flowing at a...Ch. 8 - Prob. 8.55PCh. 8 - Prob. 8.57PCh. 8 - A gas stream containing n-hexane in nitrogen with...Ch. 8 - A mixture of n-hexane vapor and air leaves a...Ch. 8 - An equimolar liquid mixture of n-pentane and...Ch. 8 - A liquid stream containing 50.0 mole% benzene and...Ch. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - An aqueous slurry at 30°C containing 20.0 wt%...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - A liquid is placed in a wcll-insulatcd container,...Ch. 8 - A small pharmaceutical firm plans to manufacture a...Ch. 8 - Freeze drying is a technique for dehydrating...Ch. 8 - The manufacturers of a new oatmeal product want to...Ch. 8 - Freeze concentration is used to produce a...Ch. 8 - A mixture containing 35.0 mole% n-butane and the...Ch. 8 - A liquid mixture of benzene and toluene containing...Ch. 8 - Prob. 8.79PCh. 8 - An outside-air sample is taken on a day when the...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - Wet solids pass through a continuous dryer. Hot...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.93PCh. 8 - The heat of solution of ammonia in water at 1 atm...Ch. 8 - Prob. 8.96PCh. 8 - Sodium hydroxide is dissolved in enough water to...Ch. 8 - A sulfuric acid solution is labeled 8 N (where 1 N...Ch. 8 - You are about to dilute 2.00 mol of 100% sulfuric...Ch. 8 - Prob. 8.100PCh. 8 - A 0.1 mole% caustic soda (NaOH) solution is to be...Ch. 8 - Prob. 8.102PCh. 8 - Ortho-phosphoric acid (H3PO4) is produced as a...Ch. 8 - Prob. 8.104PCh. 8 - Fifty milliliters of 100% H2SO4 at 25°C and 84.2...Ch. 8 - Prob. 8.106PCh. 8 - One g-mole of pure liquid sulfuric acid at...Ch. 8 - Prob. 8.108PCh. 8 - Prob. 8.110PCh. 8 - Prob. 8.111PCh. 8 - Taking as references pure liquid sulfuric acid at...Ch. 8 - Prob. 8.113PCh. 8 - An NH3-H2O mixture containing 60wt% NH3 is brought...Ch. 8 - Prob. 8.115P
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- a. From a consideration of the following reactions, calculate AH; for methane, CH4 (g). (1) C(g) + O2 (9) → CO2 (9); AH° =-1110.17 kJ (2) 2H2 (9) + O2(g) → 2H2O(1); AH® =-571.6 kJ %3D (3) H20(1) → H2O(g); AH° = 44.0 kJ (4) CH4 (9) + 202 (9) → CO2(9) + 2H2O(g); AH° =-803.0 kJ (5) C(g) → C(s); AH° =-716.7 kJ AH - kJ b. From appropriate entropy data, calculate AS" for the formation of methane from the elements. C(s) + 2H2 (9) → CH4 (9) S° (C(s)) = 5.74 J/(mol-K) S° (H2 (9)) = 130.6 J/(mol-K) S° (CH4 (9)) = 186.3 J/(mol-K) AS" : J/K c. Calculate AG; for methane at 25°C. AG; = kJ/molarrow_forwardResolve all parts otherwise I will downvotearrow_forwardFind the standard enthalpy of formation of ethyne gas, C2H2(g), given the following data: C2H2(g) + 5/2 O2(g) - 2 CO2(g) + H20(1) AH° = -1300 kJ C(s) + O2(g) – CO2(g) AH°; = -393.5 kJ H2(g) + 1/2 O2(g) - H20(1) AH°; = -285.8 kJ %3D O 227 kJ O -17 kJ 52 kJ 73 kJ 177 kJarrow_forward
- The standard enthalpy change of combustion [to CO2(g) and H2O()] at 25°C of the organic solid 9,10-phenanthrenediol, C14H10O2(s), is determined to be -6482.1 kJ mol-1. What is the Hf° of C14H10O2(s) based on this value? Use the following data: Hf° H2O () = -285.83 kJ mol-1 ; Hf° CO2(g) = -393.51 kJ mol-1arrow_forwardPlease don't provide handwritten solutionarrow_forwardWhat is the enthalpy change when 175 g of C3H8 are burned in excess O2?C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(l) H = -2220 kJa. -1.71 107 kJb. -1.79 10-3 kJc. -3.47 100 kJd. -3.89 105 kJe. -8.83 103 kJarrow_forward
- 11arrow_forwardPlease don't provide handwritten solutionarrow_forwardUse heats of formation data bellow to calculate AH° for the reaction: Ca(OH)2 (s) + H2SO 4 () → CaSO4 (s) +2 H20 (1). AH°;(Ca(OH), (s)) = -986.59 kJ/mol AH°;(H2O (1)) = -285.9 kJ/mol AH°;(H2SO4 (1) = -811.32 kJ/mol AH°;(CaSO4 (s)) = -1432.7 kJ/mol AH° = kJ eTextbook and Media Hint Type'here.to search hp 12 47 &arrow_forward
- The standard enthalpy change of combustion [to CO2(g) and H2O()] at 25°C of the organic solid isophthalic acid, C8H6O4(s), is determined to be -3185.8 kJ mol-1. What is the Hf° of C8H6O4(s) based on this value?arrow_forwardThe standard enthalpy of reaction, AH°, for the reaction: 3H2(g) + N2O3(g) = N2(g) + 3H20(1) (1) is - 941.1 kJ mol-1 What is the value for the reaction? H2(g) +1/3N2O3(g) = 1/3N2(g) + H2O(1) (2) i) -104.7 kJ mol-1. ii) - 313.7 kJ mol-1. iii) - 941.1 kJ mol-1.arrow_forwardValue Enthalpy change for one mole, (AH) -58.3 kJ mol-1 Density 1 M NaCI, (p) 1.037 g mL-1 Specific heat of 1 M NaCl solution, (C) 3.90 J g-1 K-1 Molarity of sodium hydroxide ag) and hydrochloric acid(ag) used, (c) 2.0 mol L-1 Volume of each of sodium hydroxide ag) and hydrochloric acidaq) used, (V) 25.0 mL Average neutralisation temperature rise, (AT) 11.8 °C Unrounded Rounded Calculation Equation value value Moles of H20 produced, (n) M(mol) = C(mol L-1) × VL) Aarrow_forward
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