ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
4th Edition
ISBN: 9781119249214
Author: FELDER
Publisher: INTER WILE
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Textbook Question
Chapter 8, Problem 8.95P
The heat of solution of ammonia in water at 1 atm is
Calculate the enthalpy change that accompanies the dissolution of 200 mol of
- in 400 mol of water at 25°C and 1 atm.
If you actually bubbled 200 mol of ammonia at 25°C through 400 mol of water initially at 25°C and calculated the heat released in the process as
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1. Liquid heptane is stored in a 100,000-L storage vessel that is vented directly to air. The
heptane is stored at 25°C and 1 atm pressure. The liquid is drained from the storage
vessel and all that remains in the vessel is the air saturated with heptane vapor.
a. Is the vapor in the storage vessel flammable?
b. What is the TNT equivalent for the vapor remaining in the vessel?
c. If the vapor explodes, what is the overpressure 50 m from the vessel?
d. What damage can be expected at 50 m?
2. You have decided to use a vacuum purging technique to purge oxygen from a reactor
vessel to reduce the concentration to 2.0% (mol). The reactor is 18 ft diameter and 40 ft
tall. The temperature is 80°F. Assume that the vacuum purge goes from atmospheric
pressure to 10.0 psia. How many purge cycles are required and how many total moles of
nitrogen must be used? Assume the purge is done with pure nitrogen.
3. If the purging described in problem 2 takes place using nitrogen that has 1% (mol)
oxygen in it, how many vacuum purge cycles are required? How many total moles of the
inert gas must be used?
4. If the purging described in problem 2 is done by way of a "sweep-through" purge instead
of a vacuum purge, for how long (in minutes) must the inert gas flow through the vessel
if there is a 20 psig supply of pure nitrogen available at 150 CFM (ft³/min)? How much
nitrogen must be used (lbm)?
5. Look at Figure 7-14. Determine the voltage developed between the steel nozzle and the
grounded vessel, and how much energy is stored in the nozzle. Explain the potential
hazards for cases A and B from the following table:
Case A
Case B
Hose length (ft)
75
75
Hose diameter (in)
2.0
2.0
Flow rate (gpm)
30
30
Liquid conductivity (mho/cm)
2x10-8
1x10-14
Dielectric constant
2.3
25
Density (g/cm³)
0.8
0.9
6. In Problem 5, case B, what would be the most effective way to reduce the potential
hazards in this situation?
Chapter 8 Solutions
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
Ch. 8 - 8.1. The specific internal energy of formaldehyde...Ch. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.5PCh. 8 - 8.6. Table B.7 of Appendix B gives the following...Ch. 8 - Prob. 8.7PCh. 8 - Two formulas for the heat capacity of CO are given...Ch. 8 - 8.9. Table B.2 lists values of the heat capacity...Ch. 8 - Prob. 8.10P
Ch. 8 - Chlorine gas is to be heated front 120°C and 1 atm...Ch. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Use the enthalpy function of APEx to calculate...Ch. 8 - A stream of carbon monoxide flowing at 300 kg/min...Ch. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Calculate the heat transfer (kJ) required to cool...Ch. 8 - Twenty liters of liquid n-propyl benzoate...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - A fuel gas containing 95 mole% methane and the...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Ever wonder why espresso costs much more per cup...Ch. 8 - Prob. 8.31PCh. 8 - Saturated steam at 300°C is used to heat a...Ch. 8 - Pure ethane is burned completely with preheated...Ch. 8 - An adiabatic membrane separation unit is used to...Ch. 8 - A gas containing water vapor has a dry-basis...Ch. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - In the manufacture of nitric acid, ammonia and...Ch. 8 - A natural gas containing 95 mole% methane and the...Ch. 8 - The heat capacity at constant pressure of a gas is...Ch. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Calculate the heat of vaporization of water...Ch. 8 - Polyvinylpyrrolidone (PVP) is a polymer product...Ch. 8 - Benzene vapor at 480°C is cooled and converted to...Ch. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - A stream of pure cyclopentane vapor flowing at a...Ch. 8 - Prob. 8.55PCh. 8 - Prob. 8.57PCh. 8 - A gas stream containing n-hexane in nitrogen with...Ch. 8 - A mixture of n-hexane vapor and air leaves a...Ch. 8 - An equimolar liquid mixture of n-pentane and...Ch. 8 - A liquid stream containing 50.0 mole% benzene and...Ch. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - An aqueous slurry at 30°C containing 20.0 wt%...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - A liquid is placed in a wcll-insulatcd container,...Ch. 8 - A small pharmaceutical firm plans to manufacture a...Ch. 8 - Freeze drying is a technique for dehydrating...Ch. 8 - The manufacturers of a new oatmeal product want to...Ch. 8 - Freeze concentration is used to produce a...Ch. 8 - A mixture containing 35.0 mole% n-butane and the...Ch. 8 - A liquid mixture of benzene and toluene containing...Ch. 8 - Prob. 8.79PCh. 8 - An outside-air sample is taken on a day when the...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - Wet solids pass through a continuous dryer. Hot...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.93PCh. 8 - The heat of solution of ammonia in water at 1 atm...Ch. 8 - Prob. 8.96PCh. 8 - Sodium hydroxide is dissolved in enough water to...Ch. 8 - A sulfuric acid solution is labeled 8 N (where 1 N...Ch. 8 - You are about to dilute 2.00 mol of 100% sulfuric...Ch. 8 - Prob. 8.100PCh. 8 - A 0.1 mole% caustic soda (NaOH) solution is to be...Ch. 8 - Prob. 8.102PCh. 8 - Ortho-phosphoric acid (H3PO4) is produced as a...Ch. 8 - Prob. 8.104PCh. 8 - Fifty milliliters of 100% H2SO4 at 25°C and 84.2...Ch. 8 - Prob. 8.106PCh. 8 - One g-mole of pure liquid sulfuric acid at...Ch. 8 - Prob. 8.108PCh. 8 - Prob. 8.110PCh. 8 - Prob. 8.111PCh. 8 - Taking as references pure liquid sulfuric acid at...Ch. 8 - Prob. 8.113PCh. 8 - An NH3-H2O mixture containing 60wt% NH3 is brought...Ch. 8 - Prob. 8.115P
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