Structural formua of the product formed when each alkene is treated with one equivalent of NBS in C H 2 C l 2 in presence of light has to be drawn. Concept introduction: Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene. • NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct. • Allylic susbstitution using NBS involves a net double substitution i.e, B r in NBs is exchanged by the hydrogen in alkene.

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Answer 1

Question

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

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Answer 2

Question

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

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Answer 3

Question

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

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Answer 4

Question

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

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Answer 5

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 6

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 7

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

Answer 12

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Answer 23

Ch. 8.2 - Prob. 8.1P Ch. 8.4 - Name and draw structural formulas for all...Ch. 8.4 - Using the table of bond dissociation enthalpies in...Ch. 8.5 - Prob. 8.4P Ch. 8.6 - Given the solution to Example 8.5, predict the...Ch. 8.7 - Prob. 8.6P Ch. 8.7 - Linoleic acid is shown below. What makes this...Ch. 8.7 - Prob. BQ Ch. 8.7 - Prob. CQ Ch. 8.7 - The strength of the HO bond in vitamin E is weaker...

Solution Summary: The author explains that Bromine is not good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

Chapter 8 Solutions