Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 8, Problem 8.11P
Interpretation Introduction

Interpretation:

Reason for molecular weight of perfluromethylcyclohexane is three times that of methylcyclohexane, but its boiling point is lower than that of methylcyclohexane has to be identified.

Concept introduction:

Density of haloalkanes is more as halogens have larger mass-to-volume.

The carbon-halogen bond of alkyl halide is polarised.

Dipole moment increases, as the electronegativity of halogen and bond length increases.

Haloalkanes in liquid state has a combination of attractive forces, termed as van der Waals forces.

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