EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 8, Problem 8.116EP
Interpretation Introduction
Interpretation: The type of substance that is similar to the mode of action of emulsification has to be stated.
Concept introduction: The process in which, the breakdown of large fat globules into smaller one which are water soluble is known as emulsification. The emulsifying agents help like bile acid helps in the process of emulsification.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 8 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 8.1 - Prob. 1QQCh. 8.1 - Which of the following is not a biochemical...Ch. 8.1 - The saponifiable/nonsaponifiable classification...Ch. 8.2 - Prob. 1QQCh. 8.2 - Prob. 2QQCh. 8.2 - Prob. 3QQCh. 8.2 - Prob. 4QQCh. 8.3 - Prob. 1QQCh. 8.3 - Prob. 2QQCh. 8.4 - How many structural subunits are present in the...
Ch. 8.4 - Prob. 2QQCh. 8.4 - Prob. 3QQCh. 8.4 - How many different mixed triglyceride molecules...Ch. 8.4 - Prob. 5QQCh. 8.4 - Unsaturated fatty acid residues are structural...Ch. 8.5 - Prob. 1QQCh. 8.5 - Prob. 2QQCh. 8.5 - Prob. 3QQCh. 8.6 - Prob. 1QQCh. 8.6 - Prob. 2QQCh. 8.6 - Prob. 3QQCh. 8.6 - Prob. 4QQCh. 8.6 - Prob. 5QQCh. 8.6 - Prob. 6QQCh. 8.7 - Based on biological function, phospholipids are...Ch. 8.7 - Prob. 2QQCh. 8.7 - Which of the following statements about the...Ch. 8.7 - When the head and two tails structural model is...Ch. 8.7 - Prob. 5QQCh. 8.7 - Prob. 6QQCh. 8.8 - The number of structural building blocks present...Ch. 8.8 - Prob. 2QQCh. 8.9 - Prob. 1QQCh. 8.9 - Which of the following types of membrane lipids...Ch. 8.9 - Prob. 3QQCh. 8.10 - Which of the following is a correct representation...Ch. 8.10 - Prob. 2QQCh. 8.10 - Prob. 3QQCh. 8.10 - Prob. 4QQCh. 8.10 - Which of the following membrane transport...Ch. 8.11 - Which of the following statements concerning bile...Ch. 8.11 - Which of the following statements concerning...Ch. 8.12 - Which of the following statements concerning...Ch. 8.12 - Prob. 2QQCh. 8.12 - Prob. 3QQCh. 8.13 - Prob. 1QQCh. 8.13 - Aspirin reduces inflammation and fever by...Ch. 8.13 - Prob. 3QQCh. 8.14 - Prob. 1QQCh. 8.14 - Prob. 2QQCh. 8.14 - Prob. 3QQCh. 8.15 - In which of the following pairs of lipid types are...Ch. 8.15 - Prob. 2QQCh. 8.15 - Prob. 3QQCh. 8 - Indicate whether each of the following general...Ch. 8 - Indicate whether each of the following general...Ch. 8 - Would you expect lipids to be soluble or insoluble...Ch. 8 - Would you expect lipids to be soluble or insoluble...Ch. 8 - What is the biochemical function category for each...Ch. 8 - What is the biochemical function category for each...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Classify each of the following fatty acids as...Ch. 8 - Prob. 8.10EPCh. 8 - Prob. 8.11EPCh. 8 - Prob. 8.12EPCh. 8 - Prob. 8.13EPCh. 8 - Prob. 8.14EPCh. 8 - Classify each of the fatty acids in Problem 19-13...Ch. 8 - Prob. 8.16EPCh. 8 - Draw the condensed structural formula for the...Ch. 8 - Draw the condensed structural formula for the...Ch. 8 - Prob. 8.19EPCh. 8 - Prob. 8.20EPCh. 8 - What is the relationship between carbon chain...Ch. 8 - What is the relationship between degree of...Ch. 8 - What structural change is associated with the...Ch. 8 - Prob. 8.24EPCh. 8 - In each of the following pairs of fatty acids,...Ch. 8 - In each of the following pairs of fatty acids,...Ch. 8 - What are the four structural subunits that...Ch. 8 - Draw the general block diagram for a...Ch. 8 - Prob. 8.29EPCh. 8 - Determine the following for a triacylglycerol in...Ch. 8 - Draw the condensed structural formula of a...Ch. 8 - Draw the condensed structural formula of a...Ch. 8 - Draw block diagram structures for the four...Ch. 8 - Draw block diagram structures for the three...Ch. 8 - Identify, by common name, fatty acids present in...Ch. 8 - Identify, by common name, fatty acids present in...Ch. 8 - A mixture of triacylglycerol molecules contains...Ch. 8 - Prob. 8.38EPCh. 8 - For each of the triacylglycerol molecules in...Ch. 8 - Prob. 8.40EPCh. 8 - Prob. 8.41EPCh. 8 - Prob. 8.42EPCh. 8 - Prob. 8.43EPCh. 8 - Prob. 8.44EPCh. 8 - In a dietary context, classify each of the...Ch. 8 - In a dietary context, classify each of the...Ch. 8 - Prob. 8.47EPCh. 8 - Prob. 8.48EPCh. 8 - What are the general names for the products...Ch. 8 - What additional products are formed when a...Ch. 8 - Classify each of the reaction situations in...Ch. 8 - Prob. 8.52EPCh. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Draw condensed structural formulas for all...Ch. 8 - Why can only unsaturated triacylglycerols undergo...Ch. 8 - Prob. 8.58EPCh. 8 - How many molecules of H2 will react with one...Ch. 8 - How many molecules of H2 will react with one...Ch. 8 - Prob. 8.61EPCh. 8 - Prob. 8.62EPCh. 8 - Prob. 8.63EPCh. 8 - Prob. 8.64EPCh. 8 - Prob. 8.65EPCh. 8 - Prob. 8.66EPCh. 8 - Prob. 8.67EPCh. 8 - Prob. 8.68EPCh. 8 - The following is a block diagram for a...Ch. 8 - Prob. 8.70EPCh. 8 - What structural subunits in the block diagram for...Ch. 8 - Prob. 8.72EPCh. 8 - Prob. 8.73EPCh. 8 - Prob. 8.74EPCh. 8 - Based on the head and two tails model for the...Ch. 8 - Prob. 8.76EPCh. 8 - Prob. 8.77EPCh. 8 - Prob. 8.78EPCh. 8 - Prob. 8.79EPCh. 8 - Prob. 8.80EPCh. 8 - Prob. 8.81EPCh. 8 - Prob. 8.82EPCh. 8 - Prob. 8.83EPCh. 8 - What portion or portions of the structure of a...Ch. 8 - Which of the terms triacylglycerol,...Ch. 8 - Prob. 8.86EPCh. 8 - Which of the terms triacylglycerol,...Ch. 8 - Which of the terms triacylglycerol,...Ch. 8 - Prob. 8.89EPCh. 8 - Prob. 8.90EPCh. 8 - Prob. 8.91EPCh. 8 - Prob. 8.92EPCh. 8 - Prob. 8.93EPCh. 8 - Prob. 8.94EPCh. 8 - Indicate whether each of the following statements...Ch. 8 - Prob. 8.96EPCh. 8 - Prob. 8.97EPCh. 8 - Prob. 8.98EPCh. 8 - Prob. 8.99EPCh. 8 - Prob. 8.100EPCh. 8 - In a dietary context, what is the difference...Ch. 8 - In a dietary context, how do HDL and LDL differ in...Ch. 8 - What is the general structural characteristic...Ch. 8 - What constitutes the two outside surfaces of a...Ch. 8 - Indicate whether each of the following statements...Ch. 8 - Indicate whether each of the following statements...Ch. 8 - What is the function of unsaturation in the...Ch. 8 - Prob. 8.108EPCh. 8 - Prob. 8.109EPCh. 8 - Prob. 8.110EPCh. 8 - Prob. 8.111EPCh. 8 - Prob. 8.112EPCh. 8 - Prob. 8.113EPCh. 8 - Prob. 8.114EPCh. 8 - Prob. 8.115EPCh. 8 - Prob. 8.116EPCh. 8 - Prob. 8.117EPCh. 8 - Prob. 8.118EPCh. 8 - Prob. 8.119EPCh. 8 - Indicate whether each of the following statements...Ch. 8 - Prob. 8.121EPCh. 8 - Prob. 8.122EPCh. 8 - Prob. 8.123EPCh. 8 - Prob. 8.124EPCh. 8 - What is the medium through which bile acids are...Ch. 8 - Prob. 8.126EPCh. 8 - Prob. 8.127EPCh. 8 - Prob. 8.128EPCh. 8 - Prob. 8.129EPCh. 8 - Classify each of the following as (1) an...Ch. 8 - Prob. 8.131EPCh. 8 - Prob. 8.132EPCh. 8 - Prob. 8.133EPCh. 8 - Prob. 8.134EPCh. 8 - Prob. 8.135EPCh. 8 - Prob. 8.136EPCh. 8 - Prob. 8.137EPCh. 8 - Prob. 8.138EPCh. 8 - Prob. 8.139EPCh. 8 - Prob. 8.140EPCh. 8 - What is the major structural difference between a...Ch. 8 - What is the major structural difference between a...Ch. 8 - What structural feature distinguishes a...Ch. 8 - What structural feature distinguishes a...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Classify each of the following types of lipids as...Ch. 8 - Prob. 8.148EPCh. 8 - Prob. 8.149EPCh. 8 - Draw the condensed structural formula of a wax...Ch. 8 - Prob. 8.151EPCh. 8 - Biological waxes have a head and two tails...Ch. 8 - Prob. 8.153EPCh. 8 - Prob. 8.154EPCh. 8 - Prob. 8.155EPCh. 8 - Prob. 8.156EPCh. 8 - Prob. 8.157EPCh. 8 - Prob. 8.158EPCh. 8 - Prob. 8.159EPCh. 8 - Prob. 8.160EPCh. 8 - Prob. 8.161EPCh. 8 - Prob. 8.162EP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Synthesis of ZybanⓇ: 1. Write a mechanism for the bromination of m-chloropropiophenone. Br₂ CH2Cl2 Cl Br 2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks). 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 2: 1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how to make naproxen from the compound below. Show all intermediates and reagents in your synthesis. Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction steps would need to change/add? 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAcid Catalyzed Aromatization of Carvone: 1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown. H2SO4 HO- H₂O 2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra? 3. Why does it not matter which enantiomer of carvone is used for this reaction? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Assign this H NMRarrow_forwardPlease complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Sodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAspirin from Wintergreen: 1. In isolating the salicylic acid, why is it important to press out as much of the water as possible? Write a step-by-step mechanism for the esterification of salicylic acid with acetic anhydride catalyzed by concentrated H₂SO4. 3. Calculate the exact monoisotopic mass of aspirin showing your work. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 1: 1. What characteristic absorption band changes would you expect in the IR spectrum on going from p-isobutylacetophenone to 1-(4-isobutylphenyl)-ethanol and then to 1-(4-isobutylphenyl)-1-choroethane as you did in the experiment today? Give approximate wavenumbers associated with each functional group change. Given that the mechanism of the chlorination reaction today involves formation of a benzylic carbocation, explain why the following rearranged product is not formed. محرم محمد 3. Why do we use dilute HCl for the first step of the reaction today and concentrated HCI for the second step? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
World of ChemistryChemistryISBN:9780618562763Author:Steven S. ZumdahlPublisher:Houghton Mifflin College Div
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
World of Chemistry
Chemistry
ISBN:9780618562763
Author:Steven S. Zumdahl
Publisher:Houghton Mifflin College Div
Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY