Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 8, Problem 59P
Interpretation Introduction

Interpretation: The S stereoisomers of lactic and malic acid should be drawn.

Concept introduction:The enantiomers are identical chemical compounds that have a mirror-image relationship to each other while diastereomers do not hold mirror image relationships. The former are chiral and optically active while the latter can be chiral or achiral. Together enantiomers and diastereomers constitute the total stereoisomers of any chiral compound.

In order to assign absolute configuration of R and S, Cahn − Ingold − Prelog rules are used and the first step is to assign the priority order on the basis of atomic number. The one with highest atomic number gest highest priority and is designated as a and so on with the lowest priority group at the bottom.

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