The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial. Concept introduction: In cyclohexane, all the six carbons are sp 3 hybridized so, the expected angle for the connected atoms will be 109.5 o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

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Answer 1

Question

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

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Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Answer 2

Question

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

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Answer 3

Question

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

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Answer 4

Question

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

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Answer 5

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

Answer 6

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

Answer 7

Chapter 8, Problem 29P

a.

Interpretation Introduction

Interpretation:The structure of trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxy groups are at equatorial.

Concept introduction: In cyclohexane, all the six carbons are sp³ hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

Answer 8

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

Answer 9

b.

Interpretation Introduction

Interpretation:The flipping of chair during the transformation of trans -1,2-cyclohexanediol to corresponding disilyl ether on reacting with chlorosilane needs to be explained by structural models.

Concept introduction:In cyclohexane, all the six carbons are sp3 hybridized so, the expected angle for the connected atoms will be 109.5o . The most stable conformation of cyclohexane will be the one in which the ring or angle strain is negligible and thus, making the conformation stable. In chair conformation, all the atoms are positioned in the ring in such a way that they adopt this positioning and does not experience any angle or ring strain.

Answer 10

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Answer 13

Ch. 8.1 - Prob. 8.1E Ch. 8.1 - Prob. 8.2E Ch. 8.3 - Prob. 8.4TIY Ch. 8.3 - Prob. 8.5E Ch. 8.3 - Prob. 8.6E Ch. 8.4 - Prob. 8.7E Ch. 8.5 - Prob. 8.8E Ch. 8.5 - Prob. 8.9E Ch. 8.5 - Prob. 8.10E Ch. 8.5 - Prob. 8.11E

Solution Summary: The author explains that trans -1,2-cyclohexanediol should be drawn in the chair form where both hydroxyl groups are at equatorial positions.

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