The mechanism for formation of product in indicated reaction should be written. Concept introduction: The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below. Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH 4 , LiAlH 4 . The aluminum and lithium in these reagents such as LiAlH 4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

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Answer 1

Question

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

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Answer 2

Question

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

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Answer 3

Question

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

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Answer 4

Question

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

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Answer 5

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

Answer 6

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

Answer 7

Chapter 8, Problem 39P

(a)

Interpretation Introduction

Interpretation: The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

Answer 8

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

Answer 9

(b)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon. The work up finally yields alcohol as illustrated below:

Answer 10

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

Answer 11

(c)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction:The carbonyl bond is polar with partial positive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain regents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 .

Answer 12

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

Answer 13

(d)

Interpretation Introduction

Interpretation:The mechanism for formation of product in indicated reaction should be written.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include NaBH4 , LiAlH4 . The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.1 - Prob. 8.1E Ch. 8.1 - Prob. 8.2E Ch. 8.3 - Prob. 8.4TIY Ch. 8.3 - Prob. 8.5E Ch. 8.3 - Prob. 8.6E Ch. 8.4 - Prob. 8.7E Ch. 8.5 - Prob. 8.8E Ch. 8.5 - Prob. 8.9E Ch. 8.5 - Prob. 8.10E Ch. 8.5 - Prob. 8.11E

Solution Summary: The author explains the mechanism for formation of alcohol product in indicated reaction. The carbonyl bond is polar with partial positive and partial negative charges.

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Chapter 8 Solutions