Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 38PS
Draw the resonance structures for the formate ion, HCO2−, and find the formal charge on each atom. If an H+ ion is attached to HCO2− (to form formic acid), does it attach to C or O?
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Consider the Lewis structure for CO. Which statement best explains which
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O is the donor atom because it is more electronegative.
O C is the donor atom because it is more electronegative.
O is the donor atom because it has a negative formal charge while C has a
positive formal charge.
C is the donor atom because it has a negative formal charge while O has a
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Chapter 8 Solutions
Chemistry & Chemical Reactivity
Ch. 8.2 - Draw Lewis electron dot structures for CH3Cl...Ch. 8.2 - Prob. 8.2CYUCh. 8.2 - Prob. 8.3CYUCh. 8.2 - Prob. 8.4CYUCh. 8.3 - Prob. 8.5CYUCh. 8.4 - Draw resonance structures for the bicarbonate ion,...Ch. 8.5 - Sketch the Lewis structures for CIF2+ and CIF2....Ch. 8.6 - What is the shape of the dichloromethane (CH2C12)...Ch. 8.6 - Give the electron-pair geometry and molecular...Ch. 8.6 - Draw the Lewis structure for lCl2, and then decide...
Ch. 8.7 - For each of the following pairs of bonds, decide...Ch. 8.7 - Draw the resonance structures for SCN. What are...Ch. 8.8 - For each of the following molecules, decide...Ch. 8.8 - The electrostatic potential surface for SOCl2 is...Ch. 8.9 - Using the bond dissociation enthalpies in Table...Ch. 8.10 - Prob. 1.1ACPCh. 8.10 - Do any of the atoms in an ibuprofen molecule have...Ch. 8.10 - What is the most polar bond in the molecule?
Ch. 8.10 - Prob. 1.4ACPCh. 8.10 - Prob. 1.5ACPCh. 8.10 - Prob. 1.6ACPCh. 8.10 - Are there any 120° bond angles in ibuprofen? Any...Ch. 8.10 - Prob. 1.8ACPCh. 8.10 - Prob. 2.2ACPCh. 8.10 - Calculate the difference in electronegativity...Ch. 8.10 - Predict the bond dissociation enthalpy for a...Ch. 8.10 - Prob. 3.3ACPCh. 8 - Give the periodic group number and number of...Ch. 8 - Give the periodic group number and number of...Ch. 8 - For elements in Groups 4A-7A of the periodic...Ch. 8 - Prob. 4PSCh. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Show all possible resonance structures for each of...Ch. 8 - Show all possible resonance structures for each of...Ch. 8 - Prob. 11PSCh. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Prob. 18PSCh. 8 - Prob. 19PSCh. 8 - The following molecules or ions all have three...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Give approximate values for the indicated bond...Ch. 8 - Give approximate values for the indicated bond...Ch. 8 - Phenylalanine is one of the natural amino acids...Ch. 8 - Acetylacetone has the structure shown here....Ch. 8 - For each pair of bonds, indicate the more polar...Ch. 8 - For each of the bonds listed below, tell which...Ch. 8 - Urea, (NH2)2CO, is used in plastics and...Ch. 8 - Considering both formal charges and bond...Ch. 8 - Considering both formal charge and bond...Ch. 8 - Three resonance structures are possible for...Ch. 8 - Three resonance structures are possible for the...Ch. 8 - Compare the electron dot structures of the...Ch. 8 - Compare the electron dot structures of the...Ch. 8 - The chemistry of the nitrite ion and HNO2: (a) Two...Ch. 8 - Draw the resonance structures for the formate ion,...Ch. 8 - Prob. 39PSCh. 8 - Consider the following molecules: (a) CH4 (b)...Ch. 8 - Which of the following molecules is(are) polar?...Ch. 8 - Prob. 42PSCh. 8 - Give the bond order for each bond in the following...Ch. 8 - Prob. 44PSCh. 8 - In each pair of bonds, predict which is shorter....Ch. 8 - In each pair of bonds, predict which is shorter....Ch. 8 - Prob. 47PSCh. 8 - Compare the carbon-oxygen bond lengths in the...Ch. 8 - Consider the carbon-oxygen bond in formaldehyde...Ch. 8 - Compare the nitrogen-nitrogen bond in hydrazine,...Ch. 8 - Ethanol can be made by the reaction of ethylene...Ch. 8 - Methanol can be made by partial oxidation of...Ch. 8 - Hydrogenation reactions, which involve the...Ch. 8 - Phosgene, Cl2CO, is a highly toxic gas that was...Ch. 8 - The compound oxygen difluoride is quite reactive,...Ch. 8 - Oxygen atoms can combine with ozone to form...Ch. 8 - Prob. 57GQCh. 8 - Prob. 58GQCh. 8 - Which of the following compounds or ions do not...Ch. 8 - Prob. 60GQCh. 8 - Draw resonance structures for the formate ion,...Ch. 8 - Prob. 62GQCh. 8 - Prob. 63GQCh. 8 - What is the principle of electroneutrality? Use...Ch. 8 - Prob. 65GQCh. 8 - Draw resonance structures for the SO2 molecule,...Ch. 8 - What are the orders of the NO bonds in NO2 and...Ch. 8 - Which has the greater ONO bond angle, NO2 or NO2+?...Ch. 8 - Compare the FClF angles in CIF2+ and ClF2. Using...Ch. 8 - Draw an electron dot structure for the cyanide...Ch. 8 - Draw the electron dot structure for the sulfite...Ch. 8 - Dinitrogen monoxide, N2O, can decompose to...Ch. 8 - The equation for the combustion of gaseous...Ch. 8 - The cyanate ion, OCN, has the least...Ch. 8 - Vanillin is the flavoring agent in vanilla extract...Ch. 8 - Explain why (a) XeF2 has a linear molecular...Ch. 8 - The formula for nitryl chloride is ClNO2 (in which...Ch. 8 - Hydroxyproline is a less-common amino acid. (a)...Ch. 8 - Amides are an important class of organic...Ch. 8 - Prob. 81GQCh. 8 - The molecule shown here. 2-furylmelhanethiol, is...Ch. 8 - Dihydroxyacetone is a component of quick-tanning...Ch. 8 - It is possible to draw three resonance structures...Ch. 8 - Acrolein is used to make plastics. Suppose this...Ch. 8 - Molecules in space: (a) In addition to molecules...Ch. 8 - 1,2-Dichloroethylene can be synthesized by adding...Ch. 8 - The molecule pictured below is epinephrine, a...Ch. 8 - You are doing an experiment in the laboratory and...Ch. 8 - Prob. 90ILCh. 8 - A paper published in the research Journal Science...Ch. 8 - Uracil is one of the bases in RNA, a close...Ch. 8 - Guanine is present in both DNA and RNA. (a) What...Ch. 8 - Prob. 94ILCh. 8 - Prob. 95SCQCh. 8 - Prob. 96SCQCh. 8 - Bromine-containing species play a role in...Ch. 8 - Acrylamide, H2C=CHCONH2, is a known neurotoxin and...
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- Consider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forwardThe n-propyl cation can be formed from a molecule such as When the C–Cl bond is broken so that both electrons leave with Cl, the fragments formed are The carbon atom that had been attached to Cl is now sharing ____ electron pairs. In each shared pair the carbon atom owns ____ electron. The number of electrons that belong to carbon is ____. The formal charge on the carbon atom is ____. The correct Lewis structure for the n-propyl cation isarrow_forwardConsider the formate ion, HCO2-, which is the anion formed when formic acid lose an H+ ion. The H and the two O atoms are bonded to the central C atom. a) Draw the best Lewis structure for this ion. b) Are resonance structures needed to describe this structure? c) Would you predict that the C-O bond lengths in the formate ion would be longer or shorter relative to those in CO2?arrow_forward
- 1 ) Draw the Lewis dot structure for RbIO2RbIO2. Include all hydrogen atoms and nonbonding electrons. Show the formal charges of all atoms. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. b ) Draw the Lewis dot structure for NH4ClNH4Cl. Include all hydrogen atoms and nonbonding electrons. Show the formal charges of all atoms. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. c) Draw the Lewis dot structure for KOHKOH. Include all hydrogen atoms and nonbonding electrons. Show the formal charges of all atoms. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. d) Draw the Lewis dot structure for Sr(CN)2Sr(CN)2. Include all hydrogen atoms and nonbonding electrons. Show the formal charges of all atoms. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. e)arrow_forwardResonance can only occur when the elements in the molecule keep the same formal charge. True O Falsearrow_forwardCovalent bonds: H―HC―HO―HO═O C≡O Bond energy (kJ/mol):4364154654981080Calculate the enthalpy change (H, in kJ/mol) for the following reaction and indicate whether the reaction is exothermic or endothermic.(*BE for C═Oin CO2)(a) CH4(g)+ H2O(g)CO(g)+ 3H2(g);arrow_forward
- CO3²- Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all lone pairs of electrons. Show the formal charges of all atoms in the correct structure. To change the symbol of an atom, double-click on the atom, and enter the letter of the new atom.arrow_forwardWrite two resonance structures for the formate ion, HCO2‒. (The hydrogen and both oxygen atoms are bonded to the carbon.) What do these structures predict about the carbon-oxygen bond lengths of the formate ion? What do these structures predict about the electrical charge on the oxygen atoms?arrow_forwardConvert the condensed formula CH, CH(OH)CH(CH₂), into a Lewis structure (including all lone pair electrons). Click and drag to start drawing a structure. KU с с X 5 carrow_forward
- Draw all resonance structures for the nitryl chloride molecule, NO2CI. • Explicitly draw all H atoms. Include all valence lone pairs in your answer. Do not include overall ion charges or formal charges in your drawing. Do not draw double bonds to oxygen unless they are needed for the central atom to obey the octet rule.arrow_forwardWhy don't we draw double bonds between the Be atom and the Cl atoms in BeCl2? That would give positive formal charges to the chlorine atoms and a negative formal charge to the beryllium atom. There aren't enough electrons. That would result in more than eight electrons around beryllium. That would result in more than eight electrons around each chlorine atom. That would result in the formal charges not adding up to zero.arrow_forwardThe azide ion, N, is a symmetrical ion, in which all of the possible Lewis structures have formal charge on one or more atoms. Draw three possible Lewis structures for this ion. Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all nonbonding electrons. Show the formal charges of all atoms. Q NNNITY ¤•• Q Submit Q NENN N=N-N² N²NN с H O N S P F Br CI X Type the new charge. Press ENTER to finish editing. Press TAB to go through atoms in the structure. Previous Answers Request Answer X Incorrect; Try Again; One attempt remaining Morearrow_forward
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