Chemistry in Context
8th Edition
ISBN: 9780073522975
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 8, Problem 25Q
Interpretation Introduction
Interpretation:
Significance of “Energy from Electron Transfer” has to be given.
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2) Draw the correct chemical structure (using line-angle drawings / "line structures") from their
given IUPAC name:
a.
(E)-1-chloro-3,4,5-trimethylhex-2-ene
b. (Z)-4,5,7-trimethyloct-4-en-2-ol
C. (2E,6Z)-4-methylocta-2,6-diene
පිපිම
Draw curved arrows to represent the flow of electrons in the reaction on the left
Label the reactants on the left as either "Acid" or "Base"
(iii) Decide which direction the equilibrium arrows will point in each reaction, based on
the given pk, values
(a)
+
H-O
H
3-H
+
(c)
H"
H
+
H****H
000
44-00
NH₂
(e)
i
Дон
OH
Ө
NH
3) Label the configuration in each of the following alkenes as E, Z, or N/A (for
non-stereogenic centers).
00
E
000
N/A
E
Br
N/A
N/A
(g)
E
N/A
OH
E
(b)
Oz
N/A
Br
(d)
00
E
Z
N/A
E
(f) Oz
N/A
E
(h)
Z
N/A
Chapter 8 Solutions
Chemistry in Context
Ch. 8.1 - Prob. 8.3YTCh. 8.1 - Prob. 8.4YTCh. 8.3 - Prob. 8.9CTCh. 8.4 - Prob. 8.10CTCh. 8.4 - Prob. 8.11SCCh. 8.5 - Prob. 8.13SCCh. 8.5 - Prob. 8.14CTCh. 8.6 - Prob. 8.16CTCh. 8.7 - Prob. 8.17CTCh. 8.7 - Prob. 8.18YT
Ch. 8.7 - Prob. 8.21CTCh. 8.8 - Prob. 8.23CTCh. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - Which chemical species gets oxidized and which...Ch. 8 - What is the difference between a galvanic cell and...Ch. 8 - Two common units associated with electricity are...Ch. 8 - Consider the galvanic cell pictured. A coating of...Ch. 8 - Prob. 7QCh. 8 - a. How does the voltage from a tiny AAA alkaline...Ch. 8 - Prob. 9QCh. 8 - The mercury battery has been used extensively in...Ch. 8 - Prob. 12QCh. 8 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 8 - How does the reaction between hydrogen and oxygen...Ch. 8 - This diagram represents the hydrogen fuel cell...Ch. 8 - What is a PEM fuel cell? How does it differ from...Ch. 8 - In addition to hydrogen, methane also has been...Ch. 8 - Prob. 18QCh. 8 - Potassium and lithium both are reactive Group 1...Ch. 8 - What challenges keep hydrogen fuel cells from...Ch. 8 - Every year, 5.6 1021 kJ of energy comes to Earth...Ch. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider these three sources of light: a candle, a...Ch. 8 - Prob. 27QCh. 8 - What is the difference between an electrolytic...Ch. 8 - Provide some differences between a leadacid...Ch. 8 - Prob. 30QCh. 8 - The company ZPower is promoting its silverzinc...Ch. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - You never need to plug in Toyotas gasolinebattery...Ch. 8 - Prob. 35QCh. 8 - What is the tragedy of the commons? How does this...Ch. 8 - Hydrogen is considered an environmentally friendly...Ch. 8 - Fuel cells were invented in 1839 but never...Ch. 8 - Hydrogen and methane both can react with oxygen in...Ch. 8 - Engineers have developed a prototype fuel cell...Ch. 8 - How can the principles of green chemistry be...Ch. 8 - Prob. 42QCh. 8 - Prob. 43QCh. 8 - Small quantities of hydrogen gas can be prepared...Ch. 8 - Prob. 45QCh. 8 - Prob. 46QCh. 8 - Prob. 47QCh. 8 - Prob. 48QCh. 8 - Although Alessandro Volta is credited with the...Ch. 8 - Prob. 50QCh. 8 - If all of todays technology presently based on...Ch. 8 - Prob. 52QCh. 8 - Prob. 53QCh. 8 - Prob. 54QCh. 8 - Prob. 55Q
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- 6) Fill in the missing Acid, pKa value, or conjugate base in the table below: Acid HCI Approximate pK, -7 Conjugate Base H-C: Hydronium (H₂O') -1.75 H-O-H Carboxylic Acids (RCOOH) Ammonium (NH4) 9.24 Water (H₂O) H-O-H Alcohols (ROH) RO-H Alkynes R--H Amines 25 25 38 HOarrow_forward5) Rank the following sets of compounds in order of decreasing acidity (most acidic to least acidic), and choose the justification(s) for each ranking. (a) OH V SH я вон CH most acidic (lowst pKa) least acidic (highest pKa) Effect(s) Effect(s) Effect(s) inductive effect O inductive effect O inductive effect electronegativity electronegativity O electronegativity resonance polarizability resonance polarizability O resonance O polarizability hybridization Ohybridization O hybridization оarrow_forwardHow negatively charged organic bases are formed.arrow_forward
- Nonearrow_forward1) For the following molecules: (i) Label the indicated alkenes as either cis (Z), trans (E), or N/A (for non-stereogenic centers) by bubbling in the appropriate label on the molecule. (ii) Complete the IUPAC name located below the structure (HINT: Put the letter of the configuration in parentheses at the beginning of the name!) E z N/A ()-3,4,6-trimethylhept-2-ene E Oz O N/A ()-3-ethyl-1-fluoro-4-methylhex-3-ene E -+- N/A Me )-2,3-dimethylpent-2-ene (d) (b) E O N/A Br ()-5-bromo-1-chloro-3-ethyloct-4-ene ОЕ Z N/A Et (___)-3-ethyl-4-methylhex-3-ene E (f) Oz N/A z N/A HO (4.7)-4-(2-hydroxyethyl)-7-methylnona-4,7-dien-2-onearrow_forwardO 9:21AM Tue Mar 4 ## 64% Problem 51 of 15 Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H :0: CI. AI :CI: :CI: Cl AI Select to Add Arrows Select to Add Arrows O: Cl :CI: :0: H CI: CI CO Select to Add Arrows Select to Add Arrows :O: CI :0: Cl. 10: AIarrow_forward
- (i) Draw in the missing lone pair(s) of electrons of the reactants on the left (ii) Draw (curved) arrows to show the flow of electrons in the acid/base reaction on the left (iii) Draw the products of the acid/base on the right (iv) Select the correct label for each product as either "conjugate acid" or "conjugate base" (a) JOH OH NH₂ acid base (b) De "H conjugate acid conjugate acid conjugate base conjugate base acid base conjugate acid conjugate base conjugate acid conjugate base acid basearrow_forwardCould someone answer this NMR and explain please Comment on the general features of the 1H-NMR spectrum of isoamyl ester provided below.arrow_forwardMacmillan Learning Draw the acyl chloride that would give the ketone shown using the Friedel-Crafts acylation reaction. Select Draw Templates More с H о Cl 2Q Erase AICI₂arrow_forward
- Draw the complete mechanism for this reaction: .OH مدید OH H2SO4 + H₂O To save you some time, the starting material has been copied into the first drawing area. However, you will still need to add any other reactants or catalysts that take part in the reaction. ན ི.. OH Add/Remove step Х ด ك Click and drag to start drawing a structure.arrow_forward9:27 AM Tue Mar 4 ← Problem 64 of 15 #63% Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. 0:0 0:0 :0: N. :0: :O :0: H H. :0: Select to Add Arrows O :0: H O :0: 0:0. S. H Select to Add Arrows S :0: :0: H Harrow_forwardOrder the following organic reactions by relative rate. That is, select '1' next to the reaction that will have the fastest initial rate, select '2' next to the reaction that will have the next fastest initial rate, and so on. If two reactions will have very similar initial rates, you can select the same number next to both. If a reaction will have zero or nearly zero initial rate, don't select a number and check the box in the table instead. Note: the "Nu" in these reactions means "a generic nucleophile." ملی CI :Nu 2 он 3 H Reaction Relative Rate (Choose one) ▼ Nu :CI: zero or nearly zero Nu :Nu bi (Choose one) zero or nearly zero : Nu لی Nu :H (Choose one) zero or nearly zeroarrow_forward
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