Chemistry in Context
8th Edition
ISBN: 9780073522975
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 8, Problem 4Q
What is the difference between a galvanic cell and a true battery? Give an example for each.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 8 Solutions
Chemistry in Context
Ch. 8.1 - Prob. 8.3YTCh. 8.1 - Prob. 8.4YTCh. 8.3 - Prob. 8.9CTCh. 8.4 - Prob. 8.10CTCh. 8.4 - Prob. 8.11SCCh. 8.5 - Prob. 8.13SCCh. 8.5 - Prob. 8.14CTCh. 8.6 - Prob. 8.16CTCh. 8.7 - Prob. 8.17CTCh. 8.7 - Prob. 8.18YT
Ch. 8.7 - Prob. 8.21CTCh. 8.8 - Prob. 8.23CTCh. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - Which chemical species gets oxidized and which...Ch. 8 - What is the difference between a galvanic cell and...Ch. 8 - Two common units associated with electricity are...Ch. 8 - Consider the galvanic cell pictured. A coating of...Ch. 8 - Prob. 7QCh. 8 - a. How does the voltage from a tiny AAA alkaline...Ch. 8 - Prob. 9QCh. 8 - The mercury battery has been used extensively in...Ch. 8 - Prob. 12QCh. 8 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 8 - How does the reaction between hydrogen and oxygen...Ch. 8 - This diagram represents the hydrogen fuel cell...Ch. 8 - What is a PEM fuel cell? How does it differ from...Ch. 8 - In addition to hydrogen, methane also has been...Ch. 8 - Prob. 18QCh. 8 - Potassium and lithium both are reactive Group 1...Ch. 8 - What challenges keep hydrogen fuel cells from...Ch. 8 - Every year, 5.6 1021 kJ of energy comes to Earth...Ch. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider these three sources of light: a candle, a...Ch. 8 - Prob. 27QCh. 8 - What is the difference between an electrolytic...Ch. 8 - Provide some differences between a leadacid...Ch. 8 - Prob. 30QCh. 8 - The company ZPower is promoting its silverzinc...Ch. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - You never need to plug in Toyotas gasolinebattery...Ch. 8 - Prob. 35QCh. 8 - What is the tragedy of the commons? How does this...Ch. 8 - Hydrogen is considered an environmentally friendly...Ch. 8 - Fuel cells were invented in 1839 but never...Ch. 8 - Hydrogen and methane both can react with oxygen in...Ch. 8 - Engineers have developed a prototype fuel cell...Ch. 8 - How can the principles of green chemistry be...Ch. 8 - Prob. 42QCh. 8 - Prob. 43QCh. 8 - Small quantities of hydrogen gas can be prepared...Ch. 8 - Prob. 45QCh. 8 - Prob. 46QCh. 8 - Prob. 47QCh. 8 - Prob. 48QCh. 8 - Although Alessandro Volta is credited with the...Ch. 8 - Prob. 50QCh. 8 - If all of todays technology presently based on...Ch. 8 - Prob. 52QCh. 8 - Prob. 53QCh. 8 - Prob. 54QCh. 8 - Prob. 55Q
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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