The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation. Concept Introduction: Unimolecular nucleophilic substitution reaction ( S N 1 ) : Reaction of alkyl halide with nucleophile involves two step processes, Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate. Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product. Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage. Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond . Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital. Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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Answer 1

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Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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Answer 2

Question

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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Answer 3

Question

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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Answer 4

Question

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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Answer 5

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Answer 6

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Answer 7

Chapter 7.9, Problem 28ATS

Interpretation Introduction

Interpretation:

The carbocation intermediate has to be drawn and resonance structure has to be drawn for the carbocation.

Concept Introduction:

Unimolecular nucleophilic substitution reaction(SN1): Reaction of alkyl halide with nucleophile involves two step processes,

Loss of leaving group, where the loss of leaving group from the substrate gives a carbocation intermediate.

Nucleophilic attack: A nucleophile attacks the carbocation intermediate to afford the product.

Leaving group: It is a fragment that leaves substrate with a pair of electrons via heterolytic bond cleavage.

Nucleophile: Donates pair of electrons to positively charged substrate resulting in the formation of chemical bond.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Answer 8

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Answer 9

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Answer 11

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

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