The systematic name for the given molecules should be identified. Concept Introduction: Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word. Prefix represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne , alcohol, carboxylic acid , alcohol etc... For alkenes , suffix will be ‘ ene ’. Root word represents the longest continuous carbon skeleton of the organic molecule. When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo , if it is two cyclic structure combined then prefixed with bicyclo . Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer . If the bulky groups are in opposite side then it is trans-isomer .

Question

There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

Answer 1

Question

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ M

What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?

Answer 2

Question

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Expert Solution & Answer

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Answer 3

Question

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

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Answer 5

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 6

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 7

Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given molecules should be identified.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

Answer 13

(d)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

Answer 14

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

Answer 17

(f)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S

Answer 18

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

R and S nomenclature: it is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

Rules for assigning (R, S)- configuration:

Prioritize the four groups around the chiral center according to atomic number.

Orient the chiral center such that the least priority substituent is pointing away from the viewer.

Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The systematic name has to be identified for the given organic molecule.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

For alkenes, suffix will be ‘ene’.

Root word represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Two stereoisomers are there for an alkene molecule. It depends upon the location of bulky group (or high molecular weight) on the double bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

Answer 22

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Answer 23

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Answer 33

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

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Chapter 7 Solutions