Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction. Concept Introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E 1 and E 2 . E 1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration. r ∝ [substrate] E 2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration. r ∝ [substrate] [ base ] Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 1

Question

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 2

Question

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 3

Question

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 4

Question

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 5

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 7.6, Problem 11CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at given the concentration of substrate and reagent for a second order reaction.

Concept Introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.

r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.

r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

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Chapter 7 Solutions