(a) Interpretation: The compound, from the given pair, that has higher boiling point is to be identified. Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

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Answer 1

Question

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Answer 2

Question

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Answer 3

Question

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Answer 4

Question

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Answer 5

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

Answer 6

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Answer 7

Chapter 7, Problem 7.48P

Interpretation Introduction

(a)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of compound that has linear hydrocarbon chain is higher than the boiling point of compound that has branched chains. The strength of intermolecular interactions among linear compounds is very high.

Answer 8

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Answer 9

Interpretation Introduction

(b)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of two alkyl halides that has same number of carbon atoms depends upon the size of halide. As the size if halide increases, boiling point increases. This is because the polarity of alkyl halide increases with the increase in size of halide.

Answer 10

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

Answer 11

Interpretation Introduction

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Classify each alkyl halide as 1 , 2, or 3.Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Draw the structure of an alkyl bromide with...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.5P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.7P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the boiling point of linear hydrocarbon chains is higher than that of branched chains, and the strength of intermolecular interactions among linear compounds is high.

Concept explainers

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Chapter 7 Solutions

Solution Summary: The author explains that the boiling point of linear hydrocarbon chains is higher than that of branched chains, and the strength of intermolecular interactions among linear compounds is high.

Concept explainers

(c) Interpretation: The compound, from the given pair, that has higher boiling point is to be identified. Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.

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Chapter 7 Solutions

(c)

Interpretation: The compound, from the given pair, that has higher boiling point is to be identified.

Concept introduction: The boiling point of alkyl halides is higher than that of alkanes having the same number of carbon atoms. This is due to the presence of dipole moment in alkyl halides.