(a) Interpretation: The stronger nucleophile from the given pair is to be identified. Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high p K a value.

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Answer 1

Question

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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4. Predict the products of each of the following reactions, and indicate the nucleophile that is formed. so 2. NaOH, Br₂ 1. CH,CH,NHCH,CH pH 5 3. H₂O+ H₂O+, Cl₂

Select the correct reaction. O a. O b. ос Od. o e. 1. LAH OH OH OH OH OH OH 2. PCC 3. CH3CH2Li 4. H3O+ 1. SOCI₂ 2. (CH3CH2)2CuLi 3. H3O+ 1. CH3CH2OH, HA 2. CH3CH2MgBr 3. H3O+ 1. CH3CH2NH2, DCC 2. LAH 1. SOCI₂ 2. CH3CH2Li 3. H3O+ OH of OH of OH

What does a value of K eq greater than 1 mean?A. More reactants than products exist at equilibrium.B. More products than reactants exist at equilibrium.C. The rate of the forward reaction is high atequilibrium.D. The rate of the reverse reaction is high atequilibrium.

Answer 2

Question

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 3

Question

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 4

Question

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 5

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 6

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 7

Chapter 7, Problem 7.15P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 8

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 9

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 10

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 11

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Classify each alkyl halide as 1 , 2, or 3.Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Draw the structure of an alkyl bromide with...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.5P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.7P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

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