Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 7, Problem 7.28P
Interpretation Introduction

Interpretation:

In an expansion process find out ideal work, the thermodynamic efficiency of the process, lost work and rate of entropy generation in the process.

Concept introduction:

Expansion process is an increasing volume process. Free expansion in a process has been always irreversible. Ideal work in this process can be calculated by equation:

Ideal work during expansion:

  W=m.[ΔHTσΔS]

The efficiency of any process can be calculated by dividing the actual work required in a process to ideal work required for the same process.

η=WactualWideal

Rate of entropy generation:

  ΔSg=m.(S2S1)

Lost work calculated by the equation given below:

  Wlost=TσΔSg

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