Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 7, Problem 7.17P
Interpretation Introduction

Interpretation:

The initial temperature and work produced per mole of nitrogen gas under the given conditions needs to be calculated

Concept Introduction:

  • For an ideal gas under isentropic adiabatic conditions, the temperature and pressure are related as:

  T2T1=( P2 P1 )γ-1/γ(1)where, γ = Cp/Cv

  • The work done under isentropic conditions is:

  W = nR(T1-T2)γ-1 -----(2)

The initial temperature = 276.2C0

Work done/mole of nitrogen = 2623.9 J

Given Information:

Inlet pressure of steam, P1 = 8.5 bar

Outlet Temperature of steam T2= 150C0

Outlet pressure of steam, P2 = 1.0 bar

Explanation:

In this case, nitrogen has been assumed to behave as an ideal gas. The initial temperature can be deduced from equation (1) and the work done per mole of nitrogen can be calculated from equation (2).

The heat capacity ratio for nitrogen, i.e. Cp/Cv = 1.4

Calculation:

Step 1:

Calculate the initial temperature, T1

Based on equation (1) we have:

  T2T1=( P2 P1 )γ-1/γ150T1=(1 8.5)1.4-1/1.4 =0.543T1=276.2C0

Step 2:

Calculate the work done

Based on equation (2) for 1 mole of nitrogen we have:

  W = 1×8.314×(276.2-150)1.4-1 = 2623.9 J

Thus, the initial temperature = 276.2C0

Work done/mole of nitrogen = 2623.9 J

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